Syntheses, structures, and optical properties of Ba4MInSe6 (M=Cu, Ag)

被引：5
作者：
Yin, Wenlong [1 ,2 ,3 ]
Feng, Kai [1 ,2 ,3 ]
Hao, Wenyu [1 ,2 ,3 ]
Yao, Jiyong [1 ,2 ]
Wu, Yicheng [1 ,2 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2012年 / 192卷
基金：
中国国家自然科学基金;
关键词：
Ba4MInSe6; (M; Cu; Ag); Synthesis; Crystal structure; Optical property; PHYSICAL-PROPERTIES; CRYSTAL-STRUCTURE; ELECTRONIC-STRUCTURES; QUATERNARY; SULFIDES; EARTH; CHALCOGENIDE; GD; SM; LN;
D O I：
10.1016/j.jssc.2012.03.068
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new quaternary chalcogenides, namely Ba4MInSe6 (M=Cu, Ag), were synthesized by solid state reactions. These two isostructural compounds adopt the Ba2MnS3 structure type in the orthorhombic space group Pnma. In the structure, the M and In atoms randomly occupy one crystallographic unique metal position with the molar ratio of 1:1 The (M/In)Se-4 tetrahedra are connected to each other by corner-sharing to form one-dimensional chains along the b direction, which are separated by mono-capped trigonal prismatically coordinated Ba atoms. Based on the diffuse reflectance spectrum, the optical band gaps were determined to be 2.23(2) and 2.41(2) eV for Ba4CuInSe6 and Ba4AgInSe6, respectively. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码：168 / 171
页数：4
相关论文
共 50 条
  • [1] Ba2AgInS4 and Ba4MGa5Se12 (M = Ag, Li): syntheses, structures, and optical properties
    Yin, Wenlong
    Feng, Kai
    Mei, Dajiang
    Yao, Jiyong
    Fu, Peizhen
    Wu, Yicheng
    DALTON TRANSACTIONS, 2012, 41 (08) : 2272 - 2276
  • [2] Syntheses, structures, and optical properties of Ba4Ga4SnSe12 and Ba6Ga2SnSe11
    Yin, Wenlong
    Lin, Zuohong
    Kang, Lei
    Kang, Bin
    Deng, Jianguo
    Lin, Zheshuai
    Yao, Jiyong
    Wu, Yicheng
    DALTON TRANSACTIONS, 2015, 44 (05) : 2259 - 2266
  • [3] Syntheses, structures, optical properties, and electronic structures of Ba6Cu2GSn4S16 (G = Fe, Ni) and Sr6D2FeSn4S16 (D = Cu, Ag)
    Zhang, Lingyun
    Mei, Dajiang
    Wu, Yuanwang
    Shen, Chenfei
    Hu, Wenxin
    Zhang, Lujia
    Li, Jinjin
    Wu, Yuandong
    He, Xiao
    JOURNAL OF SOLID STATE CHEMISTRY, 2019, 272 : 69 - 77
  • [4] Syntheses, structures, optical properties, and electronic structures of KBaMSe3 (M = As, Sb)
    Yin, Wenlong
    Feng, Kai
    Kang, Lei
    Kang, Bin
    Deng, Jianguo
    Lin, Zheshuai
    Yao, Jiyong
    Wu, Yicheng
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 617 : 287 - 291
  • [5] Syntheses, Structures, and Electronic Properties of Ba3FeUS6 and Ba3AgUS6
    Mesbah, Adel
    Malliakas, Christos D.
    Lebegue, Sebastien
    Sarjeant, Amy A.
    Stojko, Wojciech
    Koscielski, Lukasz A.
    Ibers, James A.
    INORGANIC CHEMISTRY, 2014, 53 (06) : 2899 - 2903
  • [6] Synthesis, Structure and Bonding, Optical Properties of Ba4MTrQ6 (M= Cu, Ag; Tr= Ga, In; Q= S, Se)
    Lei, Xiao-Wu
    Yang, Min
    Xia, Sheng-Qing
    Liu, Xiao-Cun
    Pan, Ming-Yan
    Li, Xin
    Tao, Xu-Tang
    CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (04) : 1123 - 1131
  • [7] Different clusters within the Ba4M4-xA2Te9 (M = Cu, Ag, Au; A = Si, Ge) series: Crystal structures and transport properties
    Cui, Yanjie
    Mayasree, Oottil
    Assoud, Abdeljalil
    Kleinke, Holger
    JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 493 (1-2) : 70 - 76
  • [8] Ba3LnInS6 (Ln = Pr, Sm, Gd, Yb) and Ba2LnGaS5 (Ln = Pr, Nd): Syntheses, Structures, and Magnetic and Optical Properties
    Feng, Kai
    Shi, Youguo
    Yin, Wenlong
    Wang, Wendong
    Yao, Jiyong
    Wu, Yicheng
    INORGANIC CHEMISTRY, 2012, 51 (20) : 11144 - 11149
  • [9] Synthesis, crystal structure, linear and nonlinear optical properties of quaternary sulfides Ba6(Cu2X)Ge4S16 (X=Mg, Mn, Cd)
    Cicirello, Gary
    Wu, Kui
    Wang, Jian
    JOURNAL OF SOLID STATE CHEMISTRY, 2021, 300
  • [10] Syntheses, structures, bonding, and optical properties of trinuclear cluster iodides:: M3(μ3-I)2(μ-dppm)3•I (M = Cu, Ag), dppm = bis(diphenylphosphino)methane)
    Zhou, WB
    Dong, ZC
    Song, JL
    Zeng, HY
    Cao, R
    Guo, GC
    Huang, JS
    Li, J
    JOURNAL OF CLUSTER SCIENCE, 2002, 13 (01) : 119 - 136
12345