Flammability of vulcanizates of diene rubbers

被引:24
作者
Rybinski, Przemyslaw [1 ]
Janowska, Grazyna [2 ]
Kucharska-Jastrzabek, Agnieszka [2 ]
Pajak, Agnieszka [2 ]
Wojcik, Iwona [3 ]
Wesolek, Dorota [4 ]
Bujnowicz, Krzysztof [4 ]
机构
[1] Jan Kochanowski Univ Humanities & Sci Kielce, Dept Management & Protect Environm, Kielce, Poland
[2] Tech Univ Lodz, Inst Polymer & Dye Technol, PL-90924 Lodz, Poland
[3] Jan Kochanowski Univ Humanities & Sci Kielce, Inst Geog, Kielce, Poland
[4] Inst Nat Fibres & Med Plants, Poznan, Poland
关键词
Spatial network; Diene rubbers; Flammability; Fire hazard; Toxicometric indices; Polycyclic aromatic hydrocarbons; AROMATIZATION;
D O I
10.1007/s10973-011-1728-x
中图分类号
O414.1 [热力学];
学科分类号
摘要
This article discusses the effect of the cross-linking of diene elastomers (BR, SBR, NBR), with the use of an organic peroxide or sulfur, on their flammability and fire hazard. Flammability tests were carried out by the method of oxygen index, combustion time (in air) and ignition temperature measurements. Fire hazard was determined on the basis of test results obtained by means of a cone calorimeter. Toxicometric coefficients (RTFHco/co2 and W-LC50SM) and the emission of polycyclic aromatic hydrocarbons (PAH) were determined. Test results were interpreted from the point of view of the chemical constitution of elastomer macromolecules as well as the structure of its network structure.
引用
收藏
页码:1219 / 1224
页数:6
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