Biodiesel production from bitter almond oil as new non-edible oil feedstock

被引:35
作者
Al-Tikrity, Emaad T. B. [1 ]
Fadhil, Abdelrahman B. [2 ]
Ibraheem, Khalid K. [1 ]
机构
[1] Tikrit Univ, Coll Sci, Dept Chem, Salahaldeen, Iraq
[2] Univ Mosul, Dept Chem, Coll Sci, Ind Chem Res Lab, Mosul, Iraq
关键词
Analysis of biodiesel; biodiesel; bitter almond oil; ethanolysis; non-edible oil; properties evaluation; L. SEED OIL; ETHYL-ESTERS; CATALYZED TRANSESTERIFICATION; STERCULIA-FOETIDA; FUEL PROPERTIES; FISH-OIL; ETHANOLYSIS; OPTIMIZATION; PARAMETERS; COSOLVENT;
D O I
10.1080/15567036.2016.1243172
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Bitter almond (Prunus dulcis var. amara) seed oil was tested as new nonedible feedstock for producing ethylic biodiesel by base-catalyzed transesterification with ethanol. The oil was extracted from bitter almond seed with maximum yield of 42.0 wt%, which can be considered as significant feedstock for biodiesel production. The experimental parameters involved in the optimization process were the type and concentration of the catalyst, ethanol-to-oil molar ratio, reaction temperature, reaction time, and rate of stirring. The maximum yield of biodiesel (97.1% w/w) was obtained using 0.60 wt% KOH, 7: 1 ethanol-to-oil molar ratio, 65 degrees C reaction temperature, 60 min of reaction, and 700 rpm rate of stirring. The fuel properties of the biodiesel were within the acceptable limits prescribed by ASTM D 6751. The H-1 NMR spectroscopy assured the conversion of bitter almond oil into biodiesel. Based on these results, it was concluded that bitter almond seed oil is an acceptable non-edible feedstock for biodiesel production.
引用
收藏
页码:649 / 656
页数:8
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