Calcined MgAl-Layered Double Hydroxide/Graphene Hybrids for Capacitive Deionization

被引:67
|
作者
Ren, Qidi [1 ]
Wang, Gang [1 ]
Wu, Tingting [1 ]
He, Xin [2 ]
Wang, Jianren [1 ]
Yang, Juan [1 ]
Yu, Chang [1 ]
Qiu, Jieshan [1 ]
机构
[1] Dalian Univ Technol, PSU DUT Joint Ctr Energy Res, Sch Chem Engn, State Key Lab Fine Chem,Liaoning Key Lab Energy M, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Sch Environm Sci & Technol, Key Lab Ind Ecol & Environm Engn MOE, Dalian 116024, Peoples R China
基金
美国国家科学基金会;
关键词
HYDROTALCITE-LIKE COMPOUNDS; DOUBLE HYDROXIDES; WATER-PURIFICATION; ELECTRODE MATERIAL; CARBON ELECTRODES; AQUEOUS-SOLUTION; UREA HYDROLYSIS; ZERO CHARGE; GRAPHENE; DESALINATION;
D O I
10.1021/acs.iecr.7b04983
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Layered double hydroxides (LDHs) are a class of anionic clay materials. When calcined at a certain temperature range, LDHs decompose into corresponding mixed metal oxides (Ox), which are regarded as promising electrode materials for capacitive deionization (CDI). We have developed a simple yet efficient strategy for in situ assembly of the MgAl-Ox nanosheets on graphene (G). The as-obtained MgAl-Ox/G nanohybrids with numerous channels for the access of anion exhibited high surface area and high electrical conductivity. When used as the anode of CDI cell, MgAl-Ox/ G nanohybrids exhibited excellent cycling stability and high electrosorption capacity due to its the memory effect and oxidation resistant property.
引用
收藏
页码:6417 / 6425
页数:9
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