Rhodium-catalyzed P-P bond exchange reaction of diphosphine disulfides

被引：11

作者：

Arisawa, Mieko ^{[1
]}

Yamada, Tomoki ^{[1
]}

Tanii, Saori ^{[1
]}

Kawada, Yuta ^{[1
]}

Hashimoto, Hisako ^{[2
]}

Yamaguchi, Masahiko ^{[1
]}

机构：

[1] Tohoku Univ, Dept Organ Chem, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan

[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 93期

关键词：

CENTERED RADICALS; WHITE PHOSPHORUS; CLEAVAGE; ACID; TETRAPHENYLDIPHOSPHINE; INTERCHANGE; GLUTATHIONE; ACTIVATION; COMPLEXES; CHEMISTRY;

D O I：

10.1039/c6cc07302f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhodium-catalyzed exchange reaction of diphosphine disulfides, a diphosphine oxide, and a diphosphine is developed. Various symmetric diphosphine disulfides containing alkyl and phenyl groups are exchanged, giving equilibrium mixtures, from which unsymmetric diphosphine disulfides are readily separated by silica gel chromatography. The resulting unsymmetric diphosphine disulfide is regio-selectively added to an aldehyde.

引用

收藏

页码：13580 / 13583

页数：4

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