Impact of aluminum on the structure of geopolymers from the early stages to consolidated material

被引：41

作者：

Benavent, Virginie ^{[1
]}

Steins, Prune ^{[1
]}

Sobrados, Isabel ^{[2
]}

Sanz, Jesus ^{[2
]}

Lambertin, David ^{[1
]}

Frizon, Fabien ^{[1
]}

Rossignol, Sylvie ^{[3
]}

Poulesquen, Arnaud ^{[1
]}

机构：

[1] CEA DEN DTCD SPDE LP2C, F-30207 Bagnols Sur Ceze, France

[2] Inst Ciencia Mat Madrid, CSIC, Sor Juana Ines de la Cruz 3, Madrid 28049, Spain

[3] Ecole Natl Super Ceram Ind, SPCTS, F-87000 Limoges, France

来源：

CEMENT AND CONCRETE RESEARCH | 2016年 / 90卷

关键词：

Geopolymer; Rheology; Aluminum; Porosity; ALUMINOSILICATE SOLUTIONS; SILICATE; SI-29; METAKAOLIN; SCATTERING; BEHAVIOR; ANIONS;

D O I：

10.1016/j.cemconres.2016.09.009

中图分类号：

TU [建筑科学];

学科分类号：

0813 ;

摘要：

The aim of this study is to assess the effects of the addition of aluminum (NaAlO2) into the activating solution on the geopolymerization reactions and the characteristics of the porous network. It was established by liquid state NMR that the speciation of the aluminosilicate oligomers and then the mean degree of polymerization were modified by the addition of sodium aluminate in the activating solution. Time-resolved SAXS and rheology results on geopolymer pastes showed that the molar ratios Si/Al and (Si + Al)/Na2O in the activating solution play a major role in the geopolymer properties at liquid and solid state. Indeed, the geopolymer percolating network appeared sooner and the properties of the porous network were dramatically changed with the addition of the NaAlO2. On the other hand, two geopolymers having identical final chemical composition but a different activating solution composition, showed to the same setting time and the same porous network characteristics. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：27 / 35

页数：9

共 34 条

[1]

Azizi S.N., 2012, IRAN J ENERGY ENV, V3, P157

[2] Hydration process and rheological properties of cement pastes modified by orthophosphate addition [J].

Bénard, P ;

Garrault, S ;

Nonat, A ;

Cau-Dit-Coumes, C .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (11) :1877-1883

[3] GEOPOLYMERS - INORGANIC POLYMERIC NEW MATERIALS [J].

DAVIDOVITS, J .

JOURNAL OF THERMAL ANALYSIS, 1991, 37 (08) :1633-1656

[4] Kinetics of geopolymerization:: Role of Al2O3 and SiO2 [J].

De Silva, P. ;

Sagoe-Crenstil, K. ;

Sirivivatnanon, V. .

CEMENT AND CONCRETE RESEARCH, 2007, 37 (04) :512-518

[5] Geopolymer technology:: the current state of the art [J].

Duxson, P. ;

Fernandez-Jimenez, A. ;

Provis, J. L. ;

Lukey, G. C. ;

Palomo, A. ;

van Deventer, J. S. J. .

JOURNAL OF MATERIALS SCIENCE, 2007, 42 (09) :2917-2933

[6] 29Si NMR study of structural ordering in aluminosilicate geopolymer gels [J].

Duxson, P ;

Provis, JL ;

Lukey, GC ;

Separovic, F ;

van Deventer, JSJ .

LANGMUIR, 2005, 21 (07) :3028-3036

[7] Understanding the relationship between geopolymer composition, microstructure and mechanical properties [J].

Duxson, P ;

Provis, JL ;

Lukey, GC ;

Mallicoat, SW ;

Kriven, WM ;

van Deventer, JSJ .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 269 (1-3) :47-58

[8] The effect of alkali and Si/Al ratio on the development of mechanical properties of metakaolin-based geopolymers [J].

Duxson, P. ;

Mallicoat, S. W. ;

Lukey, G. C. ;

Kriven, W. M. ;

van Deventer, J. S. J. .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 292 (01) :8-20

[9] Mechanical properties and compositional heterogeneities of fresh geopolymer pastes [J].

Favier, A. ;

Habert, G. ;

de Lacaillerie, J. B. d'Espinose ;

Roussel, N. .

CEMENT AND CONCRETE RESEARCH, 2013, 48 :9-16

[10] Flow properties of MK-based geopolymer pastes. A comparative study with standard Portland cement pastes [J].

Favier, Aurelie ;

Hot, Julie ;

Habert, Guillaume ;

Roussel, Nicolas ;

de Lacaillerie, Jean-Baptiste d'Espinose .

SOFT MATTER, 2014, 10 (08) :1134-1141

← 1 2 3 4 →