A bowl-shaped fullerene encapsulates a water into the cage

被引：148
作者：
Iwamatsu, S [1 ]
Uozaki, T
Kobayashi, K
Re, SY
Nagase, S
Murata, S
机构：
[1] Nagoya Univ, Grad Sch Environm Studies, Nagoya, Aichi 4648601, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 09期
关键词：
D O I：
10.1021/ja038537a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The sequential carbon?carbon bond cleaving reactions of the diketone derivative of C 60 with o-phenylenediamine give a novel bowl-shaped fullerene bearing a 20-membered ring orifice. The product reversibly encapsulates a water molecule into the fullerene cage for the first time. Copyright © 2004 American Chemical Society.
引用
收藏
页码：2668 / 2669
页数：2
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