Nanosecond laser treatment of graphene

被引:45
作者
Kiisk, Valter [1 ]
Kahro, Tauno [1 ]
Kozlova, Jekaterina [1 ]
Matisen, Leonard [1 ]
Alles, Harry [1 ]
机构
[1] Univ Tartu, Inst Phys, EE-51014 Tartu, Estonia
关键词
CVD graphene; Laser irradiation; Photoluminescence; Raman spectroscopy; RAMAN-SPECTROSCOPY;
D O I
10.1016/j.apsusc.2013.03.047
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Laser processing of graphene is of great interest for cutting, patterning and structural engineering purposes. Tunable nanosecond lasers have the advantage of being relatively widespread (compared to e. g. femtosecond or high-power continuous wave lasers). Hereby we have conducted an investigation of the impact of nanosecond laser pulses on CVD graphene. The damage produced by sufficiently strong single shots (pulse width 5 ns, wavelength 532 or 266 nm) from tunable optical parametric oscillator was investigated by the methods of scanning electron microscopy and optical microspectroscopy (Raman and fluorescence). Threshold of energy density for producing visible damage was found to be similar to 200 mJ/cm(2). For UV irradiation the threshold could be notably less depending on the origin of sample. Surprisingly strong fluorescence signal was recorded from damaged areas and is attributed to the residues of oxidized graphene. (C) 2013 Elsevier B. V. All rights reserved.
引用
收藏
页码:133 / 137
页数:5
相关论文
共 22 条
[1]  
[Anonymous], 2012, P ACM SIGSOFT 20 INT, DOI DOI 10.1145/2393596.2393656
[2]  
Bonaccorso F, 2010, NAT PHOTONICS, V4, P611, DOI [10.1038/nphoton.2010.186, 10.1038/NPHOTON.2010.186]
[3]   Quantifying Defects in Graphene via Raman Spectroscopy at Different Excitation Energies [J].
Cancado, L. G. ;
Jorio, A. ;
Martins Ferreira, E. H. ;
Stavale, F. ;
Achete, C. A. ;
Capaz, R. B. ;
Moutinho, M. V. O. ;
Lombardo, A. ;
Kulmala, T. S. ;
Ferrari, A. C. .
NANO LETTERS, 2011, 11 (08) :3190-3196
[4]   Raman Spectroscopy of Graphene Edges [J].
Casiraghi, C. ;
Hartschuh, A. ;
Qian, H. ;
Piscanec, S. ;
Georgi, C. ;
Fasoli, A. ;
Novoselov, K. S. ;
Basko, D. M. ;
Ferrari, A. C. .
NANO LETTERS, 2009, 9 (04) :1433-1441
[5]   Photoluminescence and Raman studies of graphene thin films prepared by reduction of graphene oxide [J].
Cuong, Tran Viet ;
Pham, Viet Hung ;
Tran, Quang Trung ;
Hahn, Sung Hong ;
Chung, Jin Suk ;
Shin, Eun Woo ;
Kim, Eui Jung .
MATERIALS LETTERS, 2010, 64 (03) :399-401
[6]   Quantifying pulsed laser induced damage to graphene [J].
Currie, Marc ;
Caldwell, Joshua D. ;
Bezares, Francisco J. ;
Robinson, Jeremy ;
Anderson, Travis ;
Chun, Hayden ;
Tadjer, Marko .
APPLIED PHYSICS LETTERS, 2011, 99 (21)
[7]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[8]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[9]   Making Graphene Luminescent by Oxygen Plasma Treatment [J].
Gokus, T. ;
Nair, R. R. ;
Bonetti, A. ;
Boehmler, M. ;
Lombardo, A. ;
Novoselov, K. S. ;
Geim, A. K. ;
Ferrari, A. C. ;
Hartschuh, A. .
ACS NANO, 2009, 3 (12) :3963-3968
[10]   Two-beam-laser interference mediated reduction, patterning and nanostructuring of graphene oxide for the production of a flexible humidity sensing device [J].
Guo, Li ;
Jiang, Hao-Bo ;
Shao, Rui-Qiang ;
Zhang, Yong-Lai ;
Xie, Sheng-Yi ;
Wang, Jian-Nan ;
Li, Xian-Bin ;
Jiang, Fan ;
Chen, Qi-Dai ;
Zhang, Tong ;
Sun, Hong-Bo .
CARBON, 2012, 50 (04) :1667-1673