Cu-Catalyzed Direct Amidation of Aromatic C-H Bonds: An Access to Arylamines

被引：90

作者：

Xu, Hui ^{[1
,2
,3
]}

Qiao, Xixue ^{[1
]}

Yang, Shiping ^{[2
,3
]}

Shen, Zengming ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Shanghai Normal Univ, Educ Minist, Key Lab Resource Chem, Shanghai 200234, Peoples R China

[3] Shanghai Normal Univ, Shanghai Key Lab Rare Earth Funct Mat, Shanghai 200234, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 10期

关键词：

DIRECT AMINATION; INTERMOLECULAR AMINATION; OXIDATIVE FUNCTIONALIZATION; SP(2); CHLOROAMINES; ACTIVATION; ELECTRON; HALIDES; AZOLES; ARENES;

D O I：

10.1021/jo5003592

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Cu-catalyzed aromatic C-H amidation with phthalimide under oxygen as a terminal oxidant without using additional additives has been achieved. This reaction has the broad substrate scope and shows moderate to good yields in most cases. This method is complementary to the previously reported metal-catalyzed C-H amination systems.

引用

页码：4414 / 4422

页数：9

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