Opportunities and Challenges of High-Energy Lithium Metal Batteries for Electric Vehicle Applications

被引:300
作者
Chen, Shuru [1 ]
Dai, Fang [1 ]
Cai, Mei [1 ]
机构
[1] Gen Motors Res & Dev Ctr, Warren, MI 48092 USA
关键词
SOLID-ELECTROLYTE INTERPHASE; ION BATTERIES; POUCH CELLS; CYCLE LIFE; ANODE; TEMPERATURE; LIQUID; ELECTRODEPOSITION; PERFORMANCE; DEPOSITION;
D O I
10.1021/acsenergylett.0c01545
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lithium metal batteries have great advantages over state-of-the-art lithium ion batteries in terms of energy density and cost, which present huge opportunities for long-range and low-cost electric vehicles in the future. However, the automotive industry has critical requirements on specific characteristics of battery cells, including but not limited to cycle life, working temperature range, fast discharge- charge capability, volume change, safety, and so on. In this Focus Review, we discuss both the cell- and system-level requirements and challenges of high-energy-density lithium metal batteries for future electrical vehicle applications and highlight some recent key progress in these aspects. Our main objective is to identify key strategies on how to solve these challenges and inspire more research and development effort to accelerate the practical applications of lithium metal batteries.
引用
收藏
页码:3140 / 3151
页数:12
相关论文
共 98 条
[11]   High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes [J].
Chen, Shuru ;
Zheng, Jianming ;
Yu, Lu ;
Ren, Xiaodi ;
Engelhard, Mark H. ;
Niu, Chaojiang ;
Lee, Hongkyung ;
Xu, Wu ;
Xiao, Jie ;
Liu, Jun ;
Zhang, Ji-Guang .
JOULE, 2018, 2 (08) :1548-1558
[12]   High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes [J].
Chen, Shuru ;
Zheng, Jianming ;
Mei, Donghai ;
Han, Kee Sung ;
Engelhard, Mark H. ;
Zhao, Wengao ;
Xu, Wu ;
Liu, Jun ;
Zhang, Ji-Guang .
ADVANCED MATERIALS, 2018, 30 (21)
[13]   Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review [J].
Cheng, Xin-Bing ;
Zhang, Rui ;
Zhao, Chen-Zi ;
Zhang, Qiang .
CHEMICAL REVIEWS, 2017, 117 (15) :10403-10473
[14]   Live scanning electron microscope observations of dendritic growth in lithium/polymer cells [J].
Dollé, M ;
Sannier, L ;
Beaudoin, B ;
Trentin, M ;
Tarascon, JM .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2002, 5 (12) :A286-A289
[15]  
Doughty D.H., 2012, VEHICLE BATTERY SAFE, DOI DOI 10.2172/1055366
[16]   A General Discussion of Li Ion Battery Safety [J].
Doughty, Dan ;
Roth, E. Peter .
ELECTROCHEMICAL SOCIETY INTERFACE, 2012, 21 (02) :37-44
[17]   Calendar and cycle life study of Li(NiMnCo)O2-based 18650 lithiumion batteries [J].
Ecker, Madeleine ;
Nieto, Nerea ;
Kaebitz, Stefan ;
Schmalstieg, Johannes ;
Blanke, Holger ;
Warnecke, Alexander ;
Sauer, Dirk Uwe .
JOURNAL OF POWER SOURCES, 2014, 248 :839-851
[18]   Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries [J].
Fan, Xiulin ;
Chen, Long ;
Borodin, Oleg ;
Ji, Xiao ;
Chen, Ji ;
Hou, Singyuk ;
Deng, Tao ;
Zheng, Jing ;
Yang, Chongyin ;
Liou, Sz-Chian ;
Amine, Khalil ;
Xu, Kang ;
Wang, Chunsheng .
NATURE NANOTECHNOLOGY, 2018, 13 (08) :715-+
[19]   Key Issues Hindering a Practical Lithium-Metal Anode [J].
Fang, Chengcheng ;
Wang, Xuefeng ;
Meng, Ying Shirley .
TRENDS IN CHEMISTRY, 2019, 1 (02) :152-158
[20]   Quantifying inactive lithium in lithium metal batteries [J].
Fang, Chengcheng ;
Li, Jinxing ;
Zhang, Minghao ;
Zhang, Yihui ;
Yang, Fan ;
Lee, Jungwoo Z. ;
Lee, Min-Han ;
Alvarado, Judith ;
Schroeder, Marshall A. ;
Yang, Yangyuchen ;
Lu, Bingyu ;
Williams, Nicholas ;
Ceja, Miguel ;
Yang, Li ;
Cai, Mei ;
Gu, Jing ;
Xu, Kang ;
Wang, Xuefeng ;
Meng, Ying Shirley .
NATURE, 2019, 572 (7770) :511-+