Shear induced orientation of phase segregated block copolymer/epoxy blends

被引:3
|
作者
Casaban, Leandro [1 ,2 ]
Kirsten, Martin [3 ]
Pegel, Sven [3 ]
Carrasco, Pedro M. [4 ]
Garcia, Ignacio [4 ]
Stamm, Manfred [3 ]
Kenny, Jose M. [1 ,2 ]
机构
[1] Univ Perugia, I-05100 Terni, Italy
[2] ICTP CSIC, Polymer Sci & Technol Inst, Madrid 28006, Spain
[3] Leibniz Inst Polymerforsch Dresden eV IPF, D-01069 Dresden, Germany
[4] CIDETEC Ctr Electrochem Technol, New Mat Dept, Donostia San Sebastian 20009, Spain
关键词
TEM; SAXS; Nanostructuration; Block copolymer; Thermosetting; Ordering; NANOSTRUCTURED THERMOSETTING SYSTEMS; LAMELLAR DIBLOCK COPOLYMER; SOLAR-CELLS; MORPHOLOGY; ALIGNMENT; EVOLUTION; DYNAMICS; ORDER; FILMS;
D O I
10.1016/j.eurpolymj.2013.07.008
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this work a phase segregated blend system consisting of a block copolymer (BCP) and epoxy matrix with cylindrical morphology is considered. Transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS) investigations reveal that long-ranged ordered nanostructures can be obtained under certain preparation conditions. The pre-shearing conditions are the most important factors in order to obtain regular structures. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3359 / 3365
页数:7
相关论文
共 50 条
  • [41] Phase transitions of polymer blends and block copolymer melts in thin films
    Binder, K
    POLYMERS IN CONFINED ENVIRONMENTS, 1999, 138 : 1 - 89
  • [42] Various Phase Behaviors of Weakly Interacting Binary Block Copolymer Blends
    Ahn, Hyungju
    Lee, Yonghoon
    Lee, Hoyeon
    Han, Young Soo
    Seong, Baek Seok
    Ryu, Du Yeol
    MACROMOLECULES, 2013, 46 (11) : 4454 - 4461
  • [43] Phase diagrams for block copolymer/homopolymer blends exhibiting LCST behaviour
    Lee, HK
    Kang, CK
    Zin, WC
    POLYMER, 1996, 37 (02) : 287 - 295
  • [44] Poly(hydroxyether of bisphenol A)-block-polydimethylsiloxane alternating block copolymer and its nanostructured blends with epoxy resin
    Gong, Wei
    Zeng, Ke
    Wang, Lei
    Zheng, Sixun
    POLYMER, 2008, 49 (15) : 3318 - 3326
  • [45] Influence of Osmotic Pressure on Nanostructures in Thin Films of a Weakly-Segregated Block Copolymer and Its Blends with a Homopolymer
    Chen, Yi-Fang
    Hong, Jia-Wen
    Chang, Jung-Hong
    Junisu, Belda Amelia
    Sun, Ya-Sen
    POLYMERS, 2021, 13 (15)
  • [46] Composition fluctuations of block copolymer/homopolymer blends under a uniform shear flow.
    Huang, CY
    York, OH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U675 - U675
  • [47] Electric-Field-Induced Alignment of Block Copolymer/Nanoparticle Blends
    Liedel, Clemens
    Schindler, Kerstin A.
    Pavan, Mariela J.
    Lewin, Christian
    Pester, Christian W.
    Ruppel, Markus
    Urban, Volker S.
    Shenhar, Roy
    Boeker, Alexander
    SMALL, 2013, 9 (19) : 3276 - 3281
  • [48] Structural Dynamics of Strongly Segregated Block Copolymer Electrolytes
    Oparaji, Onyekachi
    Narayanan, Suresh
    Sandy, Alec
    Ramakrishnan, Subramanian
    Hallinan, Daniel, Jr.
    MACROMOLECULES, 2018, 51 (07) : 2591 - 2603
  • [49] Shear-rate dependence of shear-induced orientation in morphology of triblock copolymer
    Shimizu, K
    Inomata, K
    Nose, T
    KOBUNSHI RONBUNSHU, 1999, 56 (09) : 565 - 570
  • [50] MACROPHASE SEPARATION IN BLOCK COPOLYMER BLENDS
    江明
    谢静薇
    于同隐
    A Monthly Journal of Science, 1983, (03) : 429 - 429