Synthesis, Crystal Structures and Properties of Two 3D CdII and ZnII Complexes with a 3-Fold Interpenetrating Feature

被引:4
作者
Lin, Hongyan [1 ]
Sui, Fangfang [1 ]
Liu, Peng [1 ]
Wang, Xiuli [1 ]
Liu, Guocheng [1 ]
机构
[1] Bohai Univ, Dept Chem, Jinzhou 121000, Peoples R China
来源
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2013年 / 34卷 / 07期
关键词
Hydrothermal synthesis; Complex; Diamondoid topology; 3-Fold interpenetrating structure; Fluorescent property; CD(II) COORDINATION NETWORKS; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; BIS-AMIDE LIGAND; POLYMERS; CLUSTERS; LUMINESCENCE; DIVERSITY; NETS;
D O I
10.5012/bkcs.2013.34.7.2138
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new 3D coordination complexes [Cd(3-bpcd)(pht)] (1) and [Zn(3-bpcd)(pht)] (2) [3-bpcd =N,N'-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, H(2)pht = phthalic acid] have been hydrothermally synthesized. X-ray diffraction analysis reveals that the complexes 1 and 2 represent a 4-connected diamondoid topology with a 3-fold interpenetrating feature. Moreover, the fluorescent properties of complexes 1 and 2 are studied.
引用
收藏
页码:2138 / 2142
页数:5
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