The dynamics of hydrogen bonds and proton transfer in zeolites - joint vistas from solid-state NMR and quantum chemistry

被引：37

作者：

Koller, H ^{[1
]}

Engelhardt, G

van Santen, RA

机构：

[1] Univ Munster, Inst Phys Chem, D-48149 Munster, Germany

[2] Univ Stuttgart, Inst Chem Technol 1, D-70550 Stuttgart, Germany

[3] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

来源：

TOPICS IN CATALYSIS | 1999年 / 9卷 / 3-4期

关键词：

zeolites; solid-state NMR; quantum-chemical calculations; acidity; hydrogen bonds; dynamics;

D O I：

10.1023/A:1019131126634

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The different aspects of zeolite Bronsted acid sites are reviewed from the perspective of solid-state NMR spectroscopy and quantum-chemical calculations. The strength of the combined use of these two methods is demonstrated. Special emphasis is dedicated to the structure and dynamics of hydrogen-bonded complexes of zeolites with H2O and CH3OH.

引用

页码：163 / 180

页数：18

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