Ligandless Suzuki-Miyaura reaction in neat water with or without native β-cyclodextrin as additive

被引：40

作者：

Decottignies, Audrey ^{[1
]}

Fihri, Aziz ^{[2
]}

Azemar, Geoffrey ^{[3
]}

Djedaini-Pilard, Florence ^{[3
]}

Len, Christophe ^{[1
]}

机构：

[1] Univ Technol Compiegne, Ctr Rech Royallieu, Transformat Integrees Mat Renouvelable EA 4297, F-60205 Compiegne, France

[2] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr KCC, Thuwal 23955, Saudi Arabia

[3] Univ Picardie Jules Verne, Lab Glucides FRE CNRS 3517, F-80033 Amiens, France

来源：

CATALYSIS COMMUNICATIONS | 2013年 / 32卷

关键词：

beta-cyclodextrin; Suzuki; Aqueous catalysis; CROSS-COUPLING REACTIONS; AQUEOUS-MEDIA; PALLADIUM; PROTOCOL; EFFICIENT; XPS;

D O I：

10.1016/j.catcom.2012.12.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient green ligand-free Suzuki cross coupling in neat water was developed by using low loading of catalyst (0.5 mol%) in neat water in the presence or not of beta-cyclodextrin (0.5 mol%) as additive at 25 degrees C and 100 degrees C respectively. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：101 / 107

页数：7

共 29 条

[1] Speciation of Pd(OAc)2 in ligandless Suzuki-Miyaura reactions [J].

Adrio, Luis A. ;

Nguyen, Bao N. ;

Guilera, Gemma ;

Livingston, Andrew G. ;

Hii, King Kuok .

CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (02) :316-323

[2] Use of "homeopathic" ligand-free palladium as catalyst for aryl-aryl coupling reactions [J].

Alimardanov, A ;

de Vondervoort, LSV ;

de Vries, AHM ;

de Vries, JG .

ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (13-15) :1812-1817

[3] Suzuki-Miyaura reactions in PEG-water solutions using Pd/BaSO4 as catalytic source [J].

de Souza, Andraea Luzia F. ;

Silva, Aires da Conceicao ;

Antunes, O. A. C. .

APPLIED ORGANOMETALLIC CHEMISTRY, 2009, 23 (01) :5-8

[4]

de Vries JG, 2003, EUR J ORG CHEM, V2003, P799

[5] Very Fast Suzuki-Miyaura Reaction Catalyzed by Pd(OAc)2 under Aerobic Conditions at Room Temperature in EGME/H2O [J].

Del Zotto, Alessandro ;

Amoroso, Francesco ;

Baratta, Walter ;

Rigo, Pierluigi .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 2009 (01) :110-116

[6]

Deng YJ, 2003, SYNTHESIS-STUTTGART, P337

[7] Suzuki-Miyaura cross-coupling coupling reactions with low catalyst loading: a green and sustainable protocol in pure water [J].

Fihri, Aziz ;

Luart, Denis ;

Len, Christophe ;

Solhy, Abderrahim ;

Chevrin, Carole ;

Polshettiwar, Vivek .

DALTON TRANSACTIONS, 2011, 40 (13) :3116-3121

[8] Microwave-assisted coupling reactions in aqueous media [J].

Fihri A. ;

Len C. .

RSC Green Chemistry, 2010, :55-90

[9]

Goodson F.E., 2004, ORG SYNTH, V10, P501

[10] Ligand effects in homogeneous Au catalysis [J].

Gorin, David J. ;

Sherry, Benjamin D. ;

Toste, F. Dean .

CHEMICAL REVIEWS, 2008, 108 (08) :3351-3378

← 1 2 3 →