Enantioselective addition of arylboronic acids to methyl 2-formylbenzoates by using a ruthenium/Me-BIPAM catalyst for synthesis of chiral 3-aryl-isobenzofuranones

被引：25

作者：

Yohda, Masaaki ^{[1
]}

Yamamoto, Yasunori ^{[2
]}

机构：

[1] Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo, Hokkaido 0608628, Japan

[2] Hokkaido Univ, Fac Engn, Div Chem Proc Engn, Sapporo, Hokkaido 0608628, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2015年 / 13卷 / 44期

关键词：

ARYL ADDITION/INTRAMOLECULAR LACTONIZATION; FRUITING-BODY FORMATION; ASYMMETRIC-SYNTHESIS; 3-SUBSTITUTED PHTHALIDES; ACCESS; 3-ARYL; ME-BIPAM; ALDEHYDES; COMPLEXES; RHODIUM; BASIDIFFERQUINONE;

D O I：

10.1039/c5ob01661d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ruthenium/Me-BIPAM-catalyzed asymmetric addition of arylboronic acids to methyl 2-formylbenzoates afforded chiral 3-aryl-isobenzofuranones. [RuCl2(p-cymene)](2)/Me-BIPAM and RuCl2(PPh3)(3)/Me-BIPAM catalyst systems tolerate a variety of functional groups and give high yields with high enantioselectivities.

引用

页码：10874 / 10880

页数：7

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