Preliminary Studies on Furfural Production from Lignocellulosics

被引:22
作者
Barbosa, Bianca Moreira [1 ]
Colodette, Jorge Luiz [2 ]
Longue Junior, Dalton [2 ]
Borges Gomes, Fernando Jose [2 ]
Martino, Daniela Correia [2 ]
机构
[1] Univ Fed Vicosa, Dept Chem, Campus Vicosa, BR-36570900 Vicosa, MG, Brazil
[2] Univ Fed Vicosa, Dept Forestry Engn, BR-36570900 Vicosa, MG, Brazil
关键词
Furfural; mineral acids; auto-hydrolysis; hemicelluloses; dissolving pulp production; DILUTE SULFURIC-ACID; ANTIOXIDANT ACTIVITY; SORGHUM STRAW; WHEAT-STRAW; HYDROLYSIS; AUTOHYDROLYSIS; OPTIMIZATION; XYLOSE; HEMICELLULOSE;
D O I
10.1080/02773813.2013.844167
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
This study focused on the production of furfural from agricultural and industrial biomass residues by a hydrodistillation process. Corncobs, sugarcane bagasse, and eucalypt wood were treated with sulfuric, hydrochloric, and phosphoric acids as catalysts, with different acid concentrations (1.5 to 5.2mol.L (-1)). In addition, the eucalypt liquor from the auto-hydrolysis, kraft-dissolving pulp production process was also investigated as a source of furfural, using sulfuric and hydrochloric acids as a catalyst (0.9 and 3.9mol.L (-1)). Furfural yields of 30.2, 25.8, and 13.9% were achieved for corncob, sugarcane bagasse, and eucalypt wood, respectively, on the basis of biomass dry weight. The efficiency of conversion from pentose to furfural using eucalypt liquor from the auto-hydrolysis kraft process was 71.5% using HCl 3.9mol.L (-1) . Due to the presence of a high amount of pentose, corncob produced the highest amount of furfural, followed by sugarcane bagasse and then eucalypt wood.
引用
收藏
页码:178 / 190
页数:13
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