Synthesis of endoperoxides by domino reactions of ketones and molecular oxygen

被引：9

作者：

Novkovic, L. ^{[1
]}

Trmcic, M. ^{[1
]}

Rodic, M. ^{[2
]}

Bihelovic, F. ^{[3
]}

Zlatar, M. ^{[4
]}

Matovic, R. ^{[4
]}

Saicic, R. N. ^{[3
]}

机构：

[1] Univ Belgrade, Fac Chem, Innovat Ctr, Belgrade 11158 118, Serbia

[2] Univ Novi Sad, Dept Chem, Novi Sad 21000, Serbia

[3] Univ Belgrade, Fac Chem, Belgrade 11158 118, Serbia

[4] ICTM Ctr Chem, Belgrade, Serbia

来源：

RSC ADVANCES | 2015年 / 5卷 / 120期

关键词：

INTEGRATION SCHEME; 2ND DERIVATIVES; SCREENING MODEL; PEROXIDES; SOLVATION; IMPLEMENTATION; APPROXIMATION; CHEMISTRY; MECHANISM; ENERGIES;

D O I：

10.1039/c5ra13476e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Domino reactions of ketones with molecular oxygen in the presence of potassium hydroxide and potassium t-butoxide afford cyclic hydroperoxy acetals (3,5-dihydroxy-1,2-dioxanes). Mixed endoperoxides can also be obtained in a three-component reaction of two ketones and oxygen.

引用

页码：99577 / 99584

页数：8

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