Short nylon-6 nanofiber reinforced transparent and high modulus thermoplastic polymeric composites

被引:53
作者
Jiang, Shaohua
Greiner, Andreas
Agarwal, Seema [1 ]
机构
[1] Univ Bayreuth, D-95440 Bayreuth, Germany
关键词
Short-fiber composites; Mechanical properties; Scanning electron microscopy (SEM); Electro-spinning; Transparency; WALLED CARBON NANOTUBES; MECHANICAL-PROPERTIES; ELECTROSPUN; FIBERS; NANOCOMPOSITES; NANOSPRINGS; ULTRATHIN; WHISKERS; TOUGH;
D O I
10.1016/j.compscitech.2013.08.011
中图分类号
TB33 [复合材料];
学科分类号
摘要
The use of small amounts (<5 wt%) of short nylon-6 nanofibers (diameter less than 200 nm) for reinforcing mechanical properties of TPU without losing its optical properties is highlighted in this work. The interaction of H-bonding type between the reinforcing fibers and the matrix polymer could provide a homogenous distribution of fibers and a strong interface leading to significant enhancement in mechanical properties (185% increase in E modulus) as shown by comparative use of TPU and PMMA as matrix polymers. The reinforcing effect of short fibers was attained without sacrificing transparency (>90% transparency in 400-800 nm range) of TPU. The effective use of short nylon-6 fibers in comparison to the long and continuous fibers is also discussed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:164 / 169
页数:6
相关论文
共 26 条
[11]   Electrospinning: A fascinating method for the preparation of ultrathin fibres [J].
Greiner, Andreas ;
Wendorff, Joachim H. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (30) :5670-5703
[12]   A Review on Oil Palm Empty Fruit Bunch Fiber-Reinforced Polymer Composite Materials [J].
Hassan, Azman ;
Salema, Arshad Adam ;
Ani, Farid Nasir ;
Abu Baker, Aznizam .
POLYMER COMPOSITES, 2010, 31 (12) :2079-2101
[13]   Novel Layer-by-Layer Procedure for Making Nylon-6 Nanofiber Reinforced High Strength, Tough, and Transparent Thermoplastic Polyurethane Composites [J].
Jiang, Shaohua ;
Duan, Gaigai ;
Hou, Haoqing ;
Greiner, Andreas ;
Agarwal, Seema .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (08) :4366-4372
[14]   Tough and Transparent Nylon-6 Electrospun Nanofiber Reinforced Melamine-Formaldehyde Composites [J].
Jiang, Shaohua ;
Hou, Haoqing ;
Greiner, Andreas ;
Agarwal, Seema .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (05) :2597-2603
[15]   Mechanical properties of composites using ultrafine electrospun fibers [J].
Kim, JS ;
Reneker, DH .
POLYMER COMPOSITES, 1999, 20 (01) :124-131
[16]   Formation and properties of nylon-6 and nylon-6/montmorillonite composite nanofibers [J].
Li, Lei ;
Bellan, Leon M. ;
Craighead, Harold G. ;
Frey, Margaret W. .
POLYMER, 2006, 47 (17) :6208-6217
[17]   Aligned electrospun cellulose fibers reinforced epoxy resin composite films with high visible light transmittance [J].
Liao, Huaqiang ;
Wu, Yiqiong ;
Wu, Meiyu ;
Zhan, Xianrong ;
Liu, Haiqing .
CELLULOSE, 2012, 19 (01) :111-119
[18]   Electrospun nanofiber reinforced and toughened composites through in situ nano-interface formation [J].
Lin, Song ;
Cai, Qing ;
Ji, Jianying ;
Sui, Gang ;
Yu, Yunhua ;
Yang, Xiaoping ;
Ma, Qi ;
Wei, Yan ;
Deng, Xuliang .
COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (15-16) :3322-3329
[19]   Morphology and mechanical properties of multiwalled carbon nanotubes reinforced nylon-6 composites [J].
Liu, TX ;
Phang, IY ;
Shen, L ;
Chow, SY ;
Zhang, WD .
MACROMOLECULES, 2004, 37 (19) :7214-7222
[20]  
Mallick P.K., 1993, Fiber-Reinforced Composites