Ultrafast charge migration by electron correlation

被引:297
作者
Cederbaum, LS [1 ]
Zobeley, J [1 ]
机构
[1] Univ Heidelberg, Inst Phys Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1016/S0009-2614(99)00508-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ultrafast charge migration in polyatomic systems driven solely by electron correlation is discussed and demonstrated. An explicit example is presented using large-scale ab initio Green's function calculations. It is expected that this mechanism is active in many systems. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:205 / 210
页数:6
相关论文
共 20 条
[1]  
BIRGE RA, 1994, MOL BIOMOLECULAR ELE
[2]   CORRELATION-EFFECTS IN THE IONIZATION OF MOLECULES - BREAKDOWN OF THE MOLECULAR-ORBITAL PICTURE [J].
CEDERBAUM, LS ;
DOMCKE, W ;
SCHIRMER, J ;
VONNIESSEN, W .
ADVANCES IN CHEMICAL PHYSICS, 1986, 65 :115-159
[3]  
CEDERBAUM LS, 1998, ENCY COMPUTATIONAL C
[4]  
CEDERBAUM LS, IN PRESS
[5]  
Fetter A. L., 1971, QUANTUM THEORY MANY
[6]  
Jortner J., 1990, Perspectives in Photosynthesis
[7]  
Jortner J., 1997, MOL ELECT
[8]   ELECTRON TRANSFERS IN CHEMISTRY AND BIOLOGY [J].
MARCUS, RA ;
SUTIN, N .
BIOCHIMICA ET BIOPHYSICA ACTA, 1985, 811 (03) :265-322
[9]   A BAND-LANCZOS METHOD FOR COMPUTING MATRIX-ELEMENTS OF A RESOLVENT [J].
MEYER, HD ;
PAL, S .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (10) :6195-6204
[10]  
Migdal A. B., 1967, THEORY FINITE FERMI