Nonprecious Metal Catalysts for Oxygen Reduction in Heterogeneous Aqueous Systems

被引：716
作者：
Gewirth, Andrew A. [1 ,2 ]
Varnell, Jason A. [1 ]
DiAscro, Angela M. [1 ]
机构：
[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA
[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Fukuoka 8190385, Japan
来源：
CHEMICAL REVIEWS | 2018年 / 118卷 / 05期
关键词：
NITROGEN-DOPED CARBON; REDUCED GRAPHENE OXIDE; N-C CATALYSTS; HIGH-PERFORMANCE ELECTROCATALYSTS; IRON-BASED CATALYSTS; HIGHLY EFFICIENT ELECTROCATALYSTS; POROUS GRAPHITIC CARBON; IN-SITU FORMATION; PEM FUEL-CELLS; MESOPOROUS CARBON;
D O I：
10.1021/acs.chemrev.7b00335
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A comprehensive review of recent advances in the field of oxygen reduction electrocatalysis utilizing nonprecious metal (NPM) catalysts is presented. Progress in the synthesis and characterization of pyrolyzed catalysts, based primarily on the transition metals Fe and Co with sources of N and C, is summarized. Several synthetic strategies to improve the catalytic activity for the oxygen reduction reaction (ORR) are highlighted. Recent work to explain the active-site structures and the ORR mechanism on pyrolyzed NPM catalysts is discussed. Additionally, the recent application of Cu-based catalysts for the ORR is reviewed. Suggestions and direction for future research to develop and understand NPM catalysts with enhanced ORR activity are provided.
引用
收藏
页码：2313 / 2339
页数：27
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