Thermal conductivity of low density carbon aerogels

被引:76
作者
Feng, Junzong [1 ]
Feng, Jian [1 ]
Zhang, Changrui [1 ]
机构
[1] Natl Univ Def Technol, Key Lab Adv Ceram Fibers & Composites, Coll Aerosp & Mat Engn, Changsha 410073, Hunan, Peoples R China
关键词
Carbon aerogels; Thermal conductivity; Low density; Pore size; ORGANIC AEROGELS; FORMALDEHYDE; RESORCINOL; TEMPERATURE; TRANSPORT; GELS;
D O I
10.1007/s10934-011-9504-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Carbon aerogels with densities ranging from 0.182 to 0.052 g/cm(3), pore sizes ranging from 88 to 227 nm, and particle diameters ranging from 20 to 13 nm were prepared. Thermal conductivity measurements by laser flash method indicate that the lowest thermal conductivity can be obtained at a density of 0.066 g/cm(3), in the temperature range from 100 to 300 A degrees C in air. The lowest thermal conductivity is 0.0263 W/m K at 200 A degrees C. The characteristic density, at which the lowest thermal conductivity can be obtained, is temperature dependent. At a higher temperature, a higher density carbon aerogel will be more efficient in the reduction of the total conductivity by reducing the radiative conductivity.
引用
收藏
页码:551 / 556
页数:6
相关论文
共 18 条
[1]   Preparation and properties of resorcinol-formaldehyde organic and carbon gels [J].
Al-Muhtaseb, SA ;
Ritter, JA .
ADVANCED MATERIALS, 2003, 15 (02) :101-+
[2]   THERMAL-PROPERTIES OF CARBON AEROGELS [J].
BOCK, V ;
NILSSON, O ;
BLUMM, J ;
FRICKE, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 185 (03) :233-239
[3]  
Carminati R, 2007, TOP APPL PHYS, V107, P15
[4]   Structural changes in carbon aerogels with high temperature treatment [J].
Hanzawa, Y ;
Hatori, H ;
Yoshizawa, N ;
Yamada, Y .
CARBON, 2002, 40 (04) :575-581
[5]   Thermal Transport Properties of Functionally Graded Carbon Aerogels [J].
Hemberger, Frank ;
Weis, Sebastian ;
Reichenauer, Gudrun ;
Ebert, Hans-Peter .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2009, 30 (04) :1357-1371
[6]   Maintenance of large surface area of alumina heated at elevated temperatures above 1300 °C by preparing silica-containing pseudoboehmite aerogel [J].
Horiuchi, T ;
Osaki, T ;
Sugiyama, T ;
Suzuki, K ;
Mori, T .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2001, 291 (03) :187-198
[7]   THERMAL-CONDUCTIVITY OF MONOLITHIC ORGANIC AEROGELS [J].
LU, X ;
ARDUINISCHUSTER, MC ;
KUHN, J ;
NILSSON, O ;
FRICKE, J ;
PEKALA, RW .
SCIENCE, 1992, 255 (5047) :971-972
[8]   THERMAL AND ELECTRICAL-CONDUCTIVITY OF MONOLITHIC CARBON AEROGELS [J].
LU, XP ;
NILSSON, O ;
FRICKE, J ;
PEKALA, RW .
JOURNAL OF APPLIED PHYSICS, 1993, 73 (02) :581-584
[9]   The control of porosity at nano scale in resorcinol formaldehyde carbon aerogels [J].
Mirzaeian, Mojtaba ;
Hall, Peter J. .
JOURNAL OF MATERIALS SCIENCE, 2009, 44 (10) :2705-2713
[10]   Influence of chemisorption on the thermal conductivity of single-wall carbon nanotubes [J].
Padgett, CW ;
Brenner, DW .
NANO LETTERS, 2004, 4 (06) :1051-1053