Molecular assembly-induced charge transfer between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene

被引：5

作者：

Wang, Chiming ^{[1
]}

Wang, Hailong ^{[1
]}

Liu, Chenxi ^{[1
]}

Qi, Dongdong ^{[1
]}

Jiang, Jianzhuang ^{[1
]}

机构：

[1] Univ Sci & Technol Beijing, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crysta, Beijing 100083, Peoples R China

来源：

INORGANIC CHEMISTRY FRONTIERS | 2019年 / 6卷 / 03期

关键词：

SUPRAMOLECULAR COMPLEX; PHOTOINDUCED ELECTRON; ENERGY-TRANSFER; PI-PI; PORPHYRIN; C-60; EFFICIENT; PHTHALOCYANINES; C-70;

D O I：

10.1039/c8qi01340c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An interaction between a mixed (phthalocyaninato)(porphyrinato) yttrium triple-decker and a fullerene in the solution state together with the solid state is clearly revealed by H-1 NMR, electronic absorption and luminescence spectroscopy, single crystal X-ray diffraction analysis results and DFT calculations. The close interface between a sandwich-type tetrapyrrole rare earth triple-decker and a fullerene in cocrystals affords stronger charge transfer (CT) and thus a more effective photoelectric conversion response than each individual.

引用

收藏

页码：654 / 658

页数：5

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