The Spectroscopic Properties of Mo5+ in ZnO-ZnF2-B2O3 Glasses

被引：6
|
作者：
Neeraja, K. [1 ]
Kumar, A. Rupesh [1 ]
Rao, T. G. V. M. [1 ]
Vijayalakshmi, P. [1 ]
Reddy, M. Rami [1 ]
机构：
[1] Acharya Nagarjuna Univ, Dept Phys, Guntur 522510, AP, India
来源：
TRANSACTIONS OF THE INDIAN CERAMIC SOCIETY | 2013年 / 72卷 / 01期
关键词：
Molybdenum-zinc-borate glasses; Optical absorption; ESR; FTIR and Raman spectra; BARIUM ALUMINOBORATE GLASSES; BORATE GLASSES; PHOSPHATE-GLASSES; STRUCTURAL ROLE; COPPER IONS; SYSTEM; TITANIUM; BEHAVIOR; SPECTRA; OXIDE;
D O I：
10.1080/0371750X.2013.794001
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The system of glass samples ZnO-ZnF2-B2O3 containing different concentrations of MoO3 (ranging from 1.0-7.0 mol%) were prepared. The glasses were characterized by optical absorption, ESR, FTIR and Raman spectral studies. The analyses of the results of the optical absorption and ESR studies indicated that the molybdenum ions coexisted in Mo5+ state with Mo6+ state in these glasses, whereas the results of the FTIR and Raman spectral studies indicated that there was an increasing degree of disorder in the glass network with increase in the concentration of MoO3.
引用
收藏
页码：24 / 28
页数：5
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