Visible light-induced carbonylation of indoles with arylsulfonyl chlorides and CO

被引：30
作者：
Li, Xiangguang [1 ,2 ]
Liang, Deqiang [1 ,2 ]
Huang, Wenzhong [1 ,2 ]
Zhou, Hongfu [1 ]
Li, Zhao [1 ]
Wang, Baoling [1 ,2 ]
Ma, Yinhai [1 ]
Wang, Hai [2 ]
机构：
[1] Kunming Univ, Dept Chem Sci & Technol, Kunming 650214, Peoples R China
[2] Kunming Univ, Key Lab Yunnan Prov Higher Educ Inst Organ Optoel, Kunming 650214, Peoples R China
来源：
TETRAHEDRON | 2016年 / 72卷 / 51期
基金：
中国国家自然科学基金;
关键词：
Indol-3-yl aryl ketones; Carbonylation; Arylsulfonyl chlorides; Indoles; Visible light photocatalysis; PALLADIUM-CATALYZED CARBONYLATION; METAL-FREE; PHOTOREDOX CATALYSIS; ARYL; ROUTE; DERIVATIVES; ACYLATION; EFFICIENT; KETONES; ACCESS;
D O I：
10.1016/j.tet.2016.11.009
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and simple strategy for the visible light-induced efficient synthesis of indol-3-yl aryl ketones from readily available arylsulfonyl chlorides and indoles with CO at room temperature was developed. This metal-free protocol has good functional group tolerance and avoids the use of transition-metal catalysts, additives, and alkaline or acidic reaction medium. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8442 / 8448
页数：7
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