TEMPO-mediated, room temperature synthesis of pure CoO nanoparticles

被引:28
作者
Lagunas, A
Payeras, AMI
Jimeno, C
Pericàs, MA
机构
[1] Inst Chem Res Catalonia ICIQ, Tarragona, Spain
[2] Univ Barcelona, Dept Quim Organ, Barcelona 08080, Spain
关键词
D O I
10.1039/b517812f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Treatment of dicobalt octacarbonyl with TEMPO in THF at room temperature, in the presence of oleic acid as the sole additive, leads to the formation of monodisperse nanoparticles ( ca. 3.0 nm diameter) of CoO; the particles agglomerate in solution at room temperature into aggregates, and this property has been used for the controlled preparation of hybrid materials.
引用
收藏
页码:1307 / 1309
页数:3
相关论文
共 30 条
[1]   Synthesis and magnetic properties of CoO nanoparticles [J].
Ghosh, M ;
Sampathkumaran, EV ;
Rao, CNR .
CHEMISTRY OF MATERIALS, 2005, 17 (09) :2348-2352
[2]  
Gouma PI, 2003, REV ADV MATER SCI, V5, P147
[3]   Controlled synthesis of Co3O4 nanoparticles through oriented aggregation [J].
He, T ;
Chen, DR ;
Jiao, XL .
CHEMISTRY OF MATERIALS, 2004, 16 (04) :737-743
[4]   Synthesis, crystal structure, and spectroscopic and magnetic properties of a new [Co4O(OOCNC9N18)6] cluster [J].
Jaitner, P ;
Veciana, J ;
Sporer, C ;
Kopacka, H ;
Wurst, K ;
Ruiz-Molina, D .
ORGANOMETALLICS, 2001, 20 (03) :568-571
[5]   (TMPO)CO(CO)2, SYNTHESIS AND X-RAY STRUCTURAL-ANALYSIS OF A PLANAR-COORDINATED COBALT (I) COMPLEX [J].
JAITNER, P ;
HUBER, W ;
GIEREN, A ;
BETZ, H .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 311 (03) :379-385
[6]  
Jin J, 2001, ANGEW CHEM INT EDIT, V40, P2135, DOI 10.1002/1521-3773(20010601)40:11<2135::AID-ANIE2135>3.0.CO
[7]  
2-O
[8]  
Klabunde KJ, 1996, NATO ASI 3 HIGH TECH, V12, P691
[9]   Pauson-Khand reactions in water [J].
Krafft, ME ;
Wright, JA ;
Boñaga, L .
CANADIAN JOURNAL OF CHEMISTRY, 2005, 83 (6-7) :1006-1016
[10]   TEMPO-promoted Pauson-Khand reaction.: Single-electron activation of cobalt-carbonyl bonds? [J].
Lagunas, A ;
Mairata i Payeras, A ;
Jimeno, C ;
Pericàs, MA .
ORGANIC LETTERS, 2005, 7 (14) :3033-3036