Synthesis, Structures and Luminescent Properties of Two Coordination Polymers Based on 5-(4-Carboxyphenyl)-2, 6-Pyridinedicarboxylic Acid

被引：5
作者：
Zhang, Wenqian [1 ]
Yu, Jiancan [1 ]
Cui, Yuanjing [1 ]
Rao, Xingtang [1 ]
Yang, Yu [1 ]
Qian, Guodong [1 ]
机构：
[1] Zhejiang Univ, State Key Lab Silicon Mat, Cyrus Tang Ctr Sensor Mat & Applicat, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Coordination polymers; Heterocycle polycarboxylate ligands; Crystal structure; Luminescence; METAL-ORGANIC FRAMEWORK; GAS;
D O I：
10.1002/zaac.201200394
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination polymers, Zn7O(cpda)3(OH)3 (1) and [Tb(H2cpda)(Hcpda)(H2O)]center dot(H2O) (2) (H3cpda = 5-(4-carboxyphenyl)-2, 6-pyridinedicarboxylic acid), were synthesized and characterized by elemental analysis, FTIR spectroscopy, TGA, PXRD, and single-crystal X-ray diffraction. Complex 1 has a 3D framework structure with high thermal stability and complex 2 exhibits 1D chain structure. Luminescent measurements indicate that complex 1 shows strong ligand-to-metal charge transfer (LMCT) luminescence, while complex 2 exhibits the characteristic emission of Tb3+ ions.
引用
收藏
页码：430 / 434
页数：5
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共 35 条
  • [1] Luminescent metal-organic frameworks
    Allendorf, M. D.
    Bauer, C. A.
    Bhakta, R. K.
    Houk, R. J. T.
    [J]. CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) : 1330 - 1352
  • [2] Lanthanide-Based Luminescent Hybrid Materials
    Binnemans, Koen
    [J]. CHEMICAL REVIEWS, 2009, 109 (09) : 4283 - 4374
  • [3] Luminescent open metal sites within a metal-organic framework for sensing small molecules
    Chen, Banglin
    Yang, Yu
    Zapata, Fatima
    Lin, Guannan
    Qian, Guodong
    Lobkovsky, Emil B.
    [J]. ADVANCED MATERIALS, 2007, 19 (13) : 1693 - +
  • [4] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules
    Chen, Banglin
    Ma, Shengqian
    Zapata, Fatima
    Fronczek, Frank R.
    Lobkovsky, Emil B.
    Zhou, Hong-Cai
    [J]. INORGANIC CHEMISTRY, 2007, 46 (04) : 1233 - 1236
  • [5] Metal-Organic Frameworks with Functional Pores for Recognition of Small Molecules
    Chen, Banglin
    Xiang, Shengchang
    Qian, Guodong
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2010, 43 (08) : 1115 - 1124
  • [6] A Luminescent Mixed-Lanthanide Metal-Organic Framework Thermometer
    Cui, Yuanjing
    Xu, Hui
    Yue, Yanfeng
    Guo, Zhiyong
    Yu, Jiancan
    Chen, Zhenxia
    Gao, Junkuo
    Yang, Yu
    Qian, Guodong
    Chen, Banglin
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (09) : 3979 - 3982
  • [7] Luminescent Functional Metal-Organic Frameworks
    Cui, Yuanjing
    Yue, Yanfeng
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1126 - 1162
  • [8] An unusually high thermal stability within a novel lanthanide 1,3,5-cyclohexanetricarboxylate framework: synthesis, structure, and thermal data
    de Lill, Daniel T.
    Cahill, Christopher L.
    [J]. CHEMICAL COMMUNICATIONS, 2006, (47) : 4946 - 4948
  • [9] Diversity of coordination architecture of metal 4,5-dicarboxyimidazole
    Fang, Rui-Qin
    Zhang, Xian-Ming
    [J]. INORGANIC CHEMISTRY, 2006, 45 (12) : 4801 - 4810
  • [10] Blue Fluorescence Emission Property of a Metal-Organic Coordination Polymer with One-Dimensional Channels
    Feng, Dan
    Liu, Shuxia
    Zhang, Wei
    Sun, Ping
    Ma, Fengji
    Zhang, Chundan
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (06): : 1133 - 1136
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