Preparation and catalytic performance of loofah sponge-derived carbon sulfonic acid for the conversion of levulinic acid to ethyl levulinate

被引：35

作者：

Li, Ning ^{[1
]}

Jiang, Shuai ^{[1
]}

Liu, Zhong-Yi ^{[1
]}

Guan, Xin-Xin ^{[1
,2
]}

Zheng, Xiu-Cheng ^{[1
,2
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan, Peoples R China

[2] Nankai Univ, Key Lab Adv Energy Mat Chem, Minist Educ, Tianjin 300071, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2019年 / 121卷

关键词：

Loofah sponge biomass; Sulfonated carbon; Solid acid; Ethyl levulinate; Esterification; Fuel additive; ESTERIFICATION;

D O I：

10.1016/j.catcom.2018.12.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The sulfonated carbon derived from loofah sponge are prepared and used as catalysts to synthesize ethyl levulinate. Various synthetic and reaction parameters on the catalytic efficiency are comparatively investigated. The acidic density of the resultant catalysts with a satisfactory reusability is as high as 1.59 mmol g(-1). The conversion of levulinic acid can reach 91% under the optimized conditions. The results show that the catalysts have great potential to be an environmentally friendly alternative solid acid for the synthesis of ethyl levulinate fuel additive.

引用

页码：11 / 14

页数：4

共 15 条

[1] Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties [J].

Budarin, Vitaly ;

Clark, James H. ;

Hardy, Jeffrey J. E. ;

Luque, Rafael ;

Milkowski, Krzysztof ;

Tavener, Stewart J. ;

Wilson, Ashley J. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3782-3786

[2] Chemically Derived Graphene Oxide: Towards Large-Area Thin-Film Electronics and Optoelectronics [J].

Eda, Goki ;

Chhowalla, Manish .

ADVANCED MATERIALS, 2010, 22 (22) :2392-2415

[3] Multifunctional Nitrogen-Doped Loofah Sponge Carbon Blocking Layer for High-Performance Rechargeable Lithium Batteries [J].

Gu, Xingxing ;

Tong, Chuan-Jia ;

Rehman, Sarish ;

Liu, Li-Min ;

Hou, Yanglong ;

Zhang, Shanqing .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (25) :15991-16001

[4] Biodiesel production from acid oils using sulfonated carbon catalyst derived from oil-cake waste [J].

Konwar, Lakhya Jyoti ;

Das, Rupali ;

Thakur, Ashim Jyoti ;

Salminen, Eero ;

Maki-Arvela, Paivi ;

Kumar, Narendra ;

Mikkola, Jyri-Pekka ;

Deka, Dhanapati .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 388 :167-176

[5] Methylene blue adsorption from aqueous solution by loofah sponge-based porous carbons [J].

Li, Zichao ;

Wang, Guoqiang ;

Zhai, Kuilu ;

He, Chengcang ;

Li, Qun ;

Guo, Peizhi .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2018, 538 :28-35

[6] The effect of different order of purification treatments on the purity of multiwalled carbon nanotubes [J].

Ling, Xinlong ;

Wei, Yizhe ;

Zou, Liming ;

Xu, Su .

APPLIED SURFACE SCIENCE, 2013, 276 :159-166

[7] Preparation of sulfonated porous carbon nanotubes/activated carbon composite beads and their adsorption of low density lipoprotein [J].

Lu, Yuemei ;

Gong, Qianming ;

Lu, Fangping ;

Liang, Ji ;

Ji, Lijun ;

Nie, Qingdong ;

Zhang, Xiumei .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2011, 22 (08) :1855-1862

[8] Activation and deactivation characteristics of sulfonated carbon catalysts [J].

Mo, Xunhua ;

Lopez, Dora E. ;

Suwannakarn, Kaewta ;

Liu, Yijun ;

Lotero, Edgar ;

Goodwin, James G., Jr. ;

Lu, Changqing .

JOURNAL OF CATALYSIS, 2008, 254 (02) :332-338

[9] Solventless esterification of fatty acids with trimethylolpropane using sulfonated amorphous carbons derived from wood powder [J].

Mun, Dasom ;

Anh Thi Hoang Vo ;

Kim, Bora ;

Shul, Yong-Gun ;

Cho, Jin Ku .

CATALYSIS COMMUNICATIONS, 2017, 96 :32-36

[10] Acid-catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon [J].

Okamura, Mai ;

Takagaki, Atsushi ;

Toda, Masakazu ;

Kondo, Junko N. ;

Domen, Kazunari ;

Tatsumi, Takashi ;

Hara, Michikazu ;

Hayashi, Shigenobu .

CHEMISTRY OF MATERIALS, 2006, 18 (13) :3039-3045

← 1 2 →