Corrosion mechanism of copper in palm biodiesel

被引：120

作者：

Fazal, M. A. ^{[1
]}

Haseeb, A. S. M. A. ^{[1
]}

Masjuki, H. H. ^{[1
]}

机构：

[1] Univ Malaya, Dept Mech Engn, Kuala Lumpur 50603, Malaysia

来源：

CORROSION SCIENCE | 2013年 / 67卷

关键词：

Copper; SEM; XRD; XPS; Pitting corrosion; ATMOSPHERIC CORROSION; QUATERNARY BRONZES; BEHAVIOR; WATER; TEMPERATURE; DEGRADATION; INHIBITION; OXIDATION; METALS; ESTER;

D O I：

10.1016/j.corsci.2012.10.006

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Biodiesel is a promising alternative fuel. However, it causes enhanced corrosion of automotive materials, especially of copper based components. In the present study, corrosion mechanism of copper was investigated by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Compositional change of biodiesel due to the exposure of copper was also investigated. Corrosion patina on copper is found to be composed of Cu2O, CuO, Cu(OH)(2) and CuCO3. Dissolved O-2, H2O, CO2 and RCOO- radical in biodiesel seem to be the leading factors in enhancing the corrosiveness of biodiesel. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：50 / 59

页数：10

共 34 条

[1] THE CORROSION OF METALS IN CONTACT WITH ESTER OILS CONTAINING WATER AT 60-DEGREES-C AND 150-DEGREES-C [J].

ARMSTRONG, RD ;

HALL, CA .

ELECTROCHIMICA ACTA, 1995, 40 (09) :1135-1147

[2] The atmospheric corrosion of quaternary bronzes: The leaching action of acid rain [J].

Bernardi, E. ;

Chiavari, C. ;

Lenza, B. ;

Martini, C. ;

Morselli, L. ;

Ospitali, F. ;

Robbiola, L. .

CORROSION SCIENCE, 2009, 51 (01) :159-170

[3] The atmospheric corrosion of quaternary bronzes: The action of stagnant rain water [J].

Chiavari, C. ;

Bernardi, E. ;

Martini, C. ;

Passarini, F. ;

Ospitali, F. ;

Robbiola, L. .

CORROSION SCIENCE, 2010, 52 (09) :3002-3010

[4] An XPS and AES study of the free corrosion of Cu-, Ni- and Zn-based alloys in synthetic sweat [J].

Colin, S ;

Beche, E ;

Berjoan, R ;

Jolibois, H ;

Chambaudet, A .

CORROSION SCIENCE, 1999, 41 (06) :1051-1065

[5] Heat transfer to metals in low pressure oxygen plasma:: application to oxidation of the 90Cu-10Zn alloy [J].

Draou, K ;

Bellakhal, N ;

Chéron, BG ;

Brisset, JL .

MATERIALS CHEMISTRY AND PHYSICS, 1999, 58 (03) :212-220

[6] Organic matter and copper corrosion by-product release: a mechanistic study [J].

Edwards, M ;

Sprague, N .

CORROSION SCIENCE, 2001, 43 (01) :1-18

[7] Degradation of automotive materials in palm biodiesel [J].

Fazal, M. A. ;

Haseeb, A. S. M. A. ;

Masjuki, H. H. .

ENERGY, 2012, 40 (01) :76-83

[8] Effect of temperature on the corrosion behavior of mild steel upon exposure to palm biodiesel [J].

Fazal, M. A. ;

Haseeb, A. S. M. A. ;

Masjuki, H. H. .

ENERGY, 2011, 36 (05) :3328-3334

[9] Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability [J].

Fazal, M. A. ;

Haseeb, A. S. M. A. ;

Masjuki, H. H. .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (02) :1314-1324

[10] Comparative corrosive characteristics of petroleum diesel and palm biodiesel for automotive materials [J].

Fazal, M. A. ;

Haseeb, A. S. M. A. ;

Masjuki, H. H. .

FUEL PROCESSING TECHNOLOGY, 2010, 91 (10) :1308-1315

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