An Iron(II) Complex of a Diamine-Bridged Bis-N-Heterocyclic Carbene

被引：49
|
作者：
Grohmann, Christoph [3 ]
Hashimoto, Takayoshi [1 ,2 ]
Froehlich, Roland [3 ]
Ohki, Yasuhiro [1 ,2 ]
Tatsumi, Kazuyuki [1 ,2 ]
Glorius, Frank [3 ]
机构：
[1] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ORGANOMETALLICS | 2012年 / 31卷 / 23期
基金：
欧洲研究理事会;
关键词：
NITROGEN ATOM-TRANSFER; CARBONYL-COMPOUNDS; ALKYL-HALIDES; EFFICIENT HYDROSILYLATION; SELECTIVE HYDROSILYLATION; DICARBENE COMPLEXES; METAL; REACTIVITY; LIGANDS; CATALYSTS;
D O I：
10.1021/om300888q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A diamine-bridged bis-N-heterocyclic carbene ligand was synthesized as imidazolium salts with chloride or triflate counteranions. Deprotonation of the chloride salt by an iron bis-amide complex or addition of the free diamine-bis-carbene ligand to FeCl2 led to the formation of an Fe(II) dichloride complex having a diamine-bis-carbene ligand, in which the iron atom is in a highly distorted octahedral geometry with weak Fe-N interactions. This iron complex was found to catalyze the hydrosilylation of acetophenone.
引用
收藏
页码：8047 / 8050
页数：4
相关论文
共 50 条
  • [21] Remarkably stable chelating bis-N-heterocyclic carbene adducts of phosphorus(I) cations
    Binder, Justin F.
    Swidan, Ala'aeddeen
    Tang, Martin
    Nguyen, Jennifer H.
    Macdonald, Charles L. B.
    CHEMICAL COMMUNICATIONS, 2015, 51 (36) : 7741 - 7744
  • [22] Molecular recognition of aliphatic oligopeptides by aromatic diamine-bridged bis(β-cyclodextrin)
    Yan Zhao
    Juan Gu
    Yong Cun Yang
    Hao Shi
    Hong You Zhu
    Rong Huang
    Bi Jing
    Research on Chemical Intermediates, 2009, 35 : 597 - 605
  • [23] Chelating Bis-N-heterocyclic Carbene-Palladium(II) Complexes for Oxidative Arene C-H Functionalization
    Desai, Sai Puneet
    Mondal, Moumita
    Choudhury, Joyanta
    ORGANOMETALLICS, 2015, 34 (12) : 2731 - 2736
  • [24] Electronic fine tuning of an iron(II) N-heterocyclic carbene complex
    Haslinger, Stefan
    Kuck, Jens
    Hahn, Eva
    Weiss, Daniel
    Pothig, Alexander
    Cokoja, Mirza
    Basset, Jean-Marie
    Kuehn, Fritz
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [25] Electrocatalytic Reduction of CO2 with Palladium Bis-N-heterocyclic Carbene Pincer Complexes
    Therrien, Jeffrey A.
    Wolf, Michael O.
    Patrick, Brian O.
    INORGANIC CHEMISTRY, 2014, 53 (24) : 12962 - 12972
  • [26] Chelated Bis-N-heterocyclic Carbene Platinum and Palladium Units as Tunable Components of Multinuclear Complexes
    Maeda, Yuri
    Hashimoto, Hideki
    Kinoshita, Isamu
    Nishioka, Takanori
    INORGANIC CHEMISTRY, 2015, 54 (02) : 448 - 459
  • [27] Spin transitions in bis(amidinato)-N-heterocyclic carbene iron(II) and iron(III) complexes
    Drake, Jessica L.
    Kaplan, Hilan Z.
    Wilding, Matthew J. T.
    Li, Bo
    Byers, Jeffery A.
    DALTON TRANSACTIONS, 2015, 44 (38) : 16703 - 16707
  • [28] Bridge functionalized bis-N-heterocyclic carbene rhodium(I) complexes and their application in catalytic hydrosilylation
    Straubinger, Claudia S.
    Jokic, Nadezda B.
    Hoegerl, Manuel P.
    Herdtweck, Eberhardt
    Herrmann, Wolfgang A.
    Kuehn, Fritz E.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (03) : 687 - 692
  • [29] Mono- and bis-N-heterocyclic carbene complexes of tantalum and niobium with high oxidation states
    Wei, ZhenHong
    Zhang, Wenbiao
    Luo, Guangming
    Xu, Feng
    Mei, YingXuan
    Cai, Hu
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (07) : 6270 - 6275
  • [30] Blue-emitting acridine-tagged silver(i)-bis-N-heterocyclic carbene
    Prabusankar, Ganesan
    Muthukumaran, Nirmala
    Vaddamanu, Moulali
    Raju, Gembali
    Velappan, Kavitha
    Sathyanarayana, Arruri
    Masaya, Yamane
    Sugiyama, Shohei
    Hisano, Kyohei
    Tsutsumi, Osamu
    RSC ADVANCES, 2019, 9 (13) : 7543 - 7550
12345