Efficient COD reduction from sulfide minerals processing wastewater using Fenton process

被引:35
作者
Meng, Xiangsong
Khoso, Sultan Ahmed
Wu, Jiangqiu
Tian, Mengjie
Kang, Jianhua
Liu, Hang
Zhang, Qingpeng
Sun, Wei
Hu, Yuehua
机构
[1] Cent S Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Hunan, Peoples R China
[2] Cent S Univ, Key Lab Hunan Prov Clean & Efficient Utilizat Str, Changsha 410083, Hunan, Peoples R China
关键词
COD; Minerals processing wastewater; Fenton process; DEGRADATION;
D O I
10.1016/j.mineng.2018.11.054
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper presents an efficient COD reduction from sulfide minerals processing wastewater using Fenton process, and the COD of the tailings dam wastewater is largely reduced from 130 mg/L to 30 mg/L, so as to meet the emission limit (COD < 60 mg/L). The effects of multiple parameters influencing the Fenton process on COD of the concentrates wastewater, such as reaction time, reaction pH, and H2O2/Fe2+ molar ratio were evaluated in detail. The mechanism of COD reduction was investigated by equilibrium speciation modelling and total organic carbon (TOC) analysis. TOC analysis shows that it is difficult for the Fenton process to oxidize all of the organics in wastewater to CO2. Pilot-scale tests were further carried out to confirm the results of the laboratory tests.
引用
收藏
页码:110 / 112
页数:3
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