Synthesis of new tripodal tri-functionalized hydrotris(indazol-1-yl)borate ligands and X-ray structures of their cyclopentadieneruthenium complexes

被引：36

作者：

Carella, A ^{[1
]}

Vives, G ^{[1
]}

Cox, T ^{[1
]}

Jaud, J ^{[1
]}

Rapenne, G ^{[1
]}

Launay, JP ^{[1
]}

机构：

[1] CNRS, NanoSci Grp, CEMES, F-31055 Toulouse 4, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 05期

关键词：

tripodal ligands; ligand design; ruthenium; indazole; stacking interactions;

D O I：

10.1002/ejic.200500851

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new tripodal ligands designed to anchor complexes onto surfaces have been synthesized. They integrate ester or thioether functions at the 6-position of the indazoles. Potassium hydrotris [6-(ethoxycarbonyl)indazolyl] borate and potassium hydrotris{6-[(ethylsulfanyl)methyl]indazolyl}borate exhibit three pendant groups oriented to anchor complexes onto an oxide and a metallic surface, respectively. Their complexation with [RuCp(CH3CN)(3)]PF6 yielded two piano-stool-shaped complexes that were characterized by X-ray diffraction. Comparison with the synthesized unfunctionalized analog showed that the three 6-substituted functions do not interfere with the coordination site and are particularly well oriented for surface deposition. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

引用

收藏

页码：980 / 987

页数：8

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