Structure and optical properties of a noncentrosymmetric borate RbSr4(BO3)3

被引：27

作者：

Xia, M. J. ^{[1
]}

Li, R. K. ^{[1
]}

机构：

[1] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Funct Crystals & Laser Technol, Beijing Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 197卷

基金：

中国国家自然科学基金;

关键词：

RbSr4(BO3)(3); Crystal growth; Apatite-like structure; Nonlinear optical properties; ALKALINE BERYLLIUM BORATE; RELATIVE PROPERTIES; MM'(4)(BO3)(3) M; NLO CRYSTALS; GROWTH; NA; M';

D O I：

10.1016/j.jssc.2012.08.058

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new noncentrosymmetric borate, RbSr4(BO3)(3) (abbreviated as RSBO), has been grown from Rb2O-B2O3-RbF flux and its crystal structure was determined by single crystal x-ray diffraction. It crystallizes in space group Ama2 with cell parameters of a=11.128(10) angstrom, 6=12.155(15) angstrom, c=6.952(7) angstrom, Z=4. The basic structural units are isolated planar BO3 groups. Second harmonic generation (SHG) test of the title compound by the Kurtz-Perry method shows that RSBO can be phase matchable with an effective SHG coefficient about two-thirds as large as that of KH2PO4 (KDP). Finally, based on the anionic group approximation, the optical properties of the title compound are compared with those of the structure-related apatite-like compounds with the formula "A(5)(TOn)(3)X". (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：366 / 369

页数：4

共 37 条

[31] Synthesis and ab initio X-ray powder diffraction structure of the new alkali and alkali earth metal borate NaCa(BO3)
Wu, L
Chen, XL
Li, XZ
Dai, L
Xu, YP
Zhao, M
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : I32 - I34
[32] Ab initio structure determination of new compound Li4CaB2O6
Wu, L
Wang, C
Chen, XL
Li, XZ
Xu, YP
Cao, YG
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (06) : 1847 - 1851
[33] Structure determination of a new compound LiCaBO3
Wu, L
Chen, XL
Li, H
He, M
Dai, L
Li, XZ
Xu, YP
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (4-5) : 1111 - 1116
[34] Nonlinear optical properties of Ca5(BO3)3F crystal
Xu, Ke
Loiseau, Pascal
Aka, Gerard
Maillard, Regine
Maillard, Alain
Taira, Takunori
[J]. OPTICS EXPRESS, 2008, 16 (22) : 17735 - 17744
[35] Zhang Guo-chun, 2004, Journal of Synthetic Crystals, V33, P490
[36] Growth and optical properties of a new nonlinear Na3La9O3(BO3)8 crystal
Zhang, Jianxiu
Wang, Guiling
Liu, Zuoliang
Wang, Lirong
Zhang, Guochun
Zhang, Xin
Wu, Yang
Fu, Peizhen
Wu, Yicheng
[J]. OPTICS EXPRESS, 2010, 18 (01): : 237 - 243
[37] Structure, growth and properties of a novel polar material, KSr4B3O9
Zhao, Wenwu
Pan, Shilie
Wang, Yongjiang
Yang, Zhihua
Wang, Xian
Han, Jian
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2012, 195 : 73 - 78

← 1 2 3 4 →