In situ synthesized TiN and TiB particulate-reinforced metal matrix composite coating was formed on Ti-3Al-2V alloy by laser cladding with a Ti/h-BN powder mixture. The phase structure, microstructure, microhardness and wear performance of the composite clad layer were analyzed by optical microscope (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscope (TEM), micro-hardness tester and wear testing machine. It has been found that the clad layer mainly consisted of alpha-Ti, TiN and Ti4N3-x at the laser power density of 120 W/mm(2); While, TiB and TiN were synthesized at the laser power densities of 150 and 180 W/mm(2). TiN and TiB were compared with dendrite and needle platelet type microstructures. The microhardness of laser clad layer was 800-1200 HV0.3 which was about 5 times of the substrate. The lost height of the substrate is almost 2 times of the clad layers. (c) 2012 Elsevier B.V. All rights reserved.
