Anion receptors that contain metals as structural units

被引：218
作者：
Amendola, Valeria [1 ]
Fabbrizzi, Luigi [1 ]
机构：
[1] Univ Pavia, Dipartimento Chim Gen, I-27100 Pavia, Italy
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 05期
关键词：
PHOTOINDUCED ELECTRON-TRANSFER; HYDROGEN-BOND; MOLECULAR RECOGNITION; TRANSITION-METAL; COORDINATION CHEMISTRY; INTRAMOLECULAR MOTIONS; SELECTIVE RECOGNITION; FLUORESCENT DETECTION; ABIOTIC GUANIDINIUM; BINDING-PROPERTIES;
D O I：
10.1039/b808264m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transition metals can be used as structural elements to build up anion receptors, enhancing H-bond donor tendencies, favouring the assembling of the molecular framework, inducing the formation of a cage. The versatile spectroscopic and electrochemical properties of the metal ion can provide a convenient signalling mechanism to communicate the occurrence of anion recognition.
引用
收藏
页码：513 / 531
页数：19
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