Novel titanium (IV) diolate complexes: Synthesis, structure and catalytic activities in ultra-high molecular weight polyethylene production

被引：28

作者：

Gagieva, Svetlana Ch ^{[1
]}

Tuskaev, Vladislav A. ^{[1
,2
]}

Fedyanin, Ivan V. ^{[2
]}

Buzin, Mikhail I. ^{[2
]}

Vasil'ev, Viktor G. ^{[2
]}

Nikiforova, Galina G. ^{[2
]}

Afanas'ev, Egor S. ^{[2
]}

Zubkevich, Sergey V. ^{[1
]}

Kurmaev, Dmitrii A. ^{[1
]}

Kolosov, Nikolay A. ^{[1
]}

Mikhaylik, Elena S. ^{[2
,3
]}

Golubev, Evgenii K. ^{[2
,3
]}

Sizov, Alexandr I. ^{[1
]}

Bulychev, Boris M. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, 1 Leninskie Gory, Moscow 119992, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, 28 Ul Vavilova, Moscow 119991, Russia

[3] Russian Acad Sci, Enikolopov Inst Synthet Polymer Mat, Profsoyuznaya Str 70, Moscow 117393, Russia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2017年 / 828卷

基金：

俄罗斯科学基金会;

关键词：

Ziegler-Natta polymerization; Ultra-high molecular weight polyethylene; Titanium; Non-metallocene; Diolate ligands; ETHYLENE POLYMERIZATION; METALLOCENE; OLIGOMERIZATION; CHLORIDE; LIGANDS; OLEFINS; SYSTEMS; DFT;

D O I：

10.1016/j.jorganchem.2016.11.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this work we describe synthesis of new chloride and alkoxo-titanium (IV) complexes 3-7 with diol O,O-type ligands from readily available and scalable precursors. Structure of complex 6 was established by X-ray diffraction. Titanium atom adopts a tetrahedral geometry formed by three oxygen atoms of ligands and one oxygen atom of isopropoxo group. The resulting complexes 3-6 are moderately or highly active in ethylene polymerization in the presence of (3Et(2)AlCl Bu2Mg} binary co-catalyst. Obtained polymers are linear polyethylene of ultrahigh molecular weight (3.7-8.8.10(6) g/mole) with a broad molecular weight distribution. Polymers are suitable for the modern methods of polymer processing - the solventless solid state formation of super high-strength (breaking strength over 2.3 GPa) and high-modulus (elastic modulus over 150 GPa) oriented films and film tapes. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：89 / 95

页数：7

共 25 条

[1] Post-Metallocenes in the Industrial Production of Polyolefins [J].

Baier, Moritz C. ;

Zuideveld, Martin A. ;

Mecking, Stefan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (37) :9722-9744

[2] Reactivity of zirconium and titanium alkoxides bidentade complexes on ethylene polymerization [J].

Basso, Nara R. de S. ;

Greco, Paula P. ;

Carone, Carlos L. P. ;

Livotto, Paolo R. ;

Simplicio, Lilian M. T. ;

da Rocha, Zenis N. ;

Galland, Griselda B. ;

dos Santos, Joao H. Z. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 267 (1-2) :129-136

[3] Titanium(IV) chloride complexes with chiral tetraaryl-1,3-dioxolane-4,5-dimethanol ligands as a new type of catalysts of ethylene polymerization [J].

Belokon', YN ;

Gagieva, SC ;

Sukhova, TA ;

Dmitriev, AB ;

Lyssenko, KA ;

Bravaya, NM ;

Bulychev, BM ;

Seebach, D .

RUSSIAN CHEMICAL BULLETIN, 2005, 54 (10) :2348-2353

[4] Mono(aryloxido)Titanium(IV) Complexes and Their Application in the Selective Dimerization of Ethylene [J].

Cazaux, Jean-Benoit ;

Braunstein, Pierre ;

Magna, Lionel ;

Saussine, Lucien ;

Olivier-Bourbigou, Helene .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (20) :2942-2950

[5] Polymerization of higher α-olefins with the catalytic system (4R,5R)-2,2-dimethyl-1,3-dioxolane-4,5-bis(perfluorophenyldimethanolate) titanium(IV) dichloride-organoaluminum compound [J].

Gagieva, S. Ch. ;

Tuskaev, V. A. ;

Smirnova, O. V. ;

Galibeev, S. S. ;

Bulychev, B. M. ;

Bravaya, N. M. .

POLYMER SCIENCE SERIES B, 2011, 53 (5-6) :299-306

[6] New bis(aryloxy)-Ti(IV) complexes and their use for the selective dimerization of ethylene to 1-butene [J].

Grasset, Fabien ;

Cazaux, Jean-Benoit ;

Magna, Lionel ;

Braunstein, Pierre ;

Olivier-Bourbigou, Helene .

DALTON TRANSACTIONS, 2012, 41 (34) :10396-10404

[7] DIRECT FORMATION OF 3,3,6,6-TETRAARYL-1,2-DIOXANS FROM 1,1-DIARYLETHYLENES AND OXYGEN, CATALYZED BY ANTIMONY(V) CHLORIDE [J].

HAYNES, RK ;

PROBERT, MKS ;

WILMOT, ID .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1978, 31 (08) :1737-1746

[8] AlR2Cl/MgR2 Combinations as Universal Cocatalysts for Ziegler-Natta, Metallocene, and Post-Metallocene Catalysts [J].

Kissin, Yury V. ;

Mink, Robert I. ;

Brandolini, Anita J. ;

Nowlin, Thomas E. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (13) :3271-3285

[9] A new cocatalyst for metallocene complexes in olefin polymerization [J].

Kissin, YV ;

Nowlin, TE ;

Mink, RI ;

Brandolini, AJ .

MACROMOLECULES, 2000, 33 (12) :4599-4601

[10] Polymethyl aromatic hydrocarbons. II. The dehydration and cyclization of 2-methyl-5-phenylhexane-2,5-diol [J].

Kloetzel, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :3405-3410

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