Carbon nanotubes/polyamide 6.6 nanostructured composites crystallization kinetic study

被引:6
作者
Ribeiro, B. [1 ]
Nohara, L. B. [1 ]
Oishi, S. S. [1 ]
Costa, M. L. [1 ,2 ]
Botelho, E. C. [1 ]
机构
[1] Sao Paulo State Univ, Dept Mat & Technol, BR-12516410 Sao Paulo, Brazil
[2] Dept Sci & Technol Aerospatiale, Div Mat, Aeronaut & Space Inst, Sao Paulo, Brazil
基金
巴西圣保罗研究基金会;
关键词
Carbon nanotubes; crystallization kinetic study; nanostructured composites; DIFFERENTIAL SCANNING CALORIMETRY; NONISOTHERMAL CRYSTALLIZATION; AVRAMI-EQUATION; NANOTUBES; NANOCOMPOSITES; POLYMER; DSC; BEHAVIORS; BLENDS; ALLOY;
D O I
10.1177/0892705711430532
中图分类号
TB33 [复合材料];
学科分类号
摘要
Compared with the traditional composites, the incorporation of carbon nanotubes into polymeric matrices can generate materials with superior properties, especially thermal, electrical and tribological properties. The aim of this study was to study the polyamide 6.6/carbon nanotubes (PA 6.6/CNT) nanostructured composites crystallization kinetics. The solution mixing technique was used to obtain the nanostructured composites studied in this work. PA 6.6 films were produced with amounts of 0.1, 0.5, and 1.0wt% (weight/weight) CNT. X-ray diffraction analyses were performed in order to determine the crystallographic properties of nanostructured composite. The nanostructured composites crystallization kinetic study was performed using the differential scanning calorimetry under isothermal and nonisothermal (dynamic) conditions. The results have shown addition of CNTs in the PA 6.6 reduces the Avrami exponent, affecting the crystallization process of the composite.
引用
收藏
页码:893 / 911
页数:19
相关论文
共 37 条
[31]  
Polyamides Selley I., 1985, ENCY POLYM SCI ENG
[32]   Non-isothermal melt crystallization kinetics for poly(trimethylene terephthalate)/poly(butylene terephthalate) blends [J].
Supaphol, P ;
Dangseeyun, N ;
Srimoaon, P .
POLYMER TESTING, 2004, 23 (02) :175-185
[33]   AC conductivity of conjugated polymer onto self-assembled aligned carbon nanotubes [J].
Valentini, L ;
Armentano, I ;
Biagiotti, J ;
Marigo, A ;
Santucci, S ;
Kenny, JM .
DIAMOND AND RELATED MATERIALS, 2004, 13 (02) :250-255
[34]   Generalization of the Avrami equation for the analysis of non-isothermal transformation kinetics.: Application to the crystallization of the Cu0.20As0.30Se0.50 alloy [J].
Vázquez, J ;
López-Alemany, PL ;
Villares, P ;
Jiménez-Garay, R .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2000, 61 (04) :493-500
[35]   Crystallization kinetics and melting behaviors of nylon 6/foliated graphite nanocomposites [J].
Weng, WG ;
Chen, GH ;
Wu, DJ .
POLYMER, 2003, 44 (26) :8119-8132
[36]   Synthesis and crystallization kinetics of silsesquioxane-based hybrid star poly(ε-caprolactone) [J].
Xu, Jianwen ;
Shi, Wenfang .
POLYMER, 2006, 47 (14) :5161-5173
[37]   Study on crystallization of nanocrystalline/amorphous Al-based alloy [J].
Zhang, Y. H. ;
Liu, Y. C. ;
Gao, Z. M. ;
Wang, D. J. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 469 (1-2) :565-570