Visible-light-induced hydroalkoxymethylation of electron-deficient alkenes by photoredox catalysis

被引：96

作者：

Miyazawa, Kazuki ^{[1
]}

Yasu, Yusuke ^{[1
]}

Koike, Takashi ^{[1
]}

Akita, Munetaka ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 65期

关键词：

SYNTHETIC APPLICATIONS; AEROBIC OXIDATION; ORGANIC-SYNTHESIS; COUPLING REACTION; AMINO RADICALS; DUAL CATALYSIS; GENERATION; FUNCTIONALIZATION; PHOTOCATALYSIS; STRATEGY;

D O I：

10.1039/c3cc42695e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroalkoxymethylation of electron-deficient alkenes using alkoxymethyltrifluoroborates by photoredox catalysis has been developed. Highly reactive alkoxymethyl radicals can be easily generated from oxidation of alkoxymethyltrifluoroborates via a visible-light-induced SET process.

引用

页码：7249 / 7251

页数：3

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