Growth of ω inclusions in Ti alloys: An X-ray diffraction study

被引:21
作者
Smilauerova, J. [1 ]
Harcuba, P. [1 ]
Pospisil, J. [1 ]
Matej, Z. [1 ]
Holy, V. [1 ]
机构
[1] Charles Univ Prague, Fac Math & Phys, Prague, Czech Republic
关键词
omega-Ti phase; Ti alloys; X-ray diffraction; Precipitates; Single crystal; PHASE-TRANSFORMATION; TITANIUM-ALLOYS; PRECIPITATION; BETA; TI-6.8MO-4.5FE-1.5AL; INSTABILITIES; KINETICS; EXAMPLE;
D O I
10.1016/j.actamat.2013.07.059
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We investigated the size and crystal structure of nanometer-sized omega inclusions in single crystals of beta-Ti alloys by X-ray diffraction pole-figure measurements and reciprocal space mapping. We studied the topotactical relation of the beta and omega crystal lattices, and from the positions and shapes of the diffraction maxima of the omega lattice determined the mean size of the omega inclusions and the misfit of the inclusion lattice with respect to the host lattice, as well as their changes during ageing. The lattice of the omega inclusions exhibits a large positive misfit already before ageing and the misfit is subsequently reduced during the ageing process. Using the theories of elasticity and X-ray scattering we simulated diffuse X-ray scattering around the beta diffraction maxima and demonstrated that the diffuse scattering is caused mainly by local elastic strains in the beta host phase around the omega inclusions. (C) 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:6635 / 6645
页数:11
相关论文
共 24 条
[1]   ON MODULATED STRUCTURE OF AGED NI-AL ALLOYS [J].
ARDELL, AJ ;
NICHOLSO.RB .
ACTA METALLURGICA, 1966, 14 (10) :1295-+
[2]   Phase transformations in Ti-6.8Mo-4.5Fe-1.5Al [J].
Azimzadeh, S ;
Rack, HJ .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1998, 29 (10) :2455-2467
[3]  
BANIA PJ, 1994, JOM-J MIN MET MAT S, V46, P16, DOI 10.1007/BF03220742
[4]   Growth kinetic model for isothermal omega phase particles in low-cost beta titanium Ti-6.8Mo-4.5Fe-1.5Al alloy [J].
Debuigne, J ;
Prima, F .
MATERIALS TRANSACTIONS, 2005, 46 (06) :1433-1435
[5]   THEORY OF DIFFUSE X-RAY-SCATTERING AND ITS APPLICATION TO STUDY OF POINT-DEFECTS AND THEIR CLUSTERS [J].
DEDERICHS, PH .
JOURNAL OF PHYSICS F-METAL PHYSICS, 1973, 3 (02) :471-496
[6]   MECHANICAL INSTABILITIES IN BCC LATTICE AND BETA TO OMEGA PHASE TRANSFORMATION [J].
DEFONTAI.D .
ACTA METALLURGICA, 1970, 18 (02) :275-&
[7]   OMEGA PHASE TRANSFORMATION IN TITANIUM ALLOYS AS AN EXAMPLE OF DISPLACEMENT CONTROLLED REACTIONS [J].
DEFONTAINE, D ;
PATON, NE ;
WILLIAMS, JC .
ACTA METALLURGICA, 1971, 19 (11) :1153-+
[8]   Experimental evidence of concurrent compositional and structural instabilities leading to ω precipitation in titanium-molybdenum alloys [J].
Devaraj, A. ;
Nag, S. ;
Srinivasan, R. ;
Williams, R. E. A. ;
Banerjee, S. ;
Banerjee, R. ;
Fraser, H. L. .
ACTA MATERIALIA, 2012, 60 (02) :596-609
[9]   Three-dimensional morphology and composition of omega precipitates in a binary titanium-molybdenum alloy [J].
Devaraj, A. ;
Williams, R. E. A. ;
Nag, S. ;
Srinivasan, R. ;
Fraser, H. L. ;
Banerjee, R. .
SCRIPTA MATERIALIA, 2009, 61 (07) :701-704
[10]   THE GROWTH OF OMEGA-PHASE INCLUSIONS IN TI-20 AT PERCENT MO AND THE COMPETITION BETWEEN ELASTIC AND SURFACE ENERGIES [J].
FRATZL, P ;
LANGMAYR, F ;
VOGL, G ;
MIEKELEY, W .
ACTA METALLURGICA ET MATERIALIA, 1991, 39 (05) :753-761