Phase Equilibrium of Three Binary Mixtures Containing NO and Components Present in Ambient Air

被引:2
作者
Zhang, Fan [1 ]
El Ahmar, Elise [1 ]
Valtz, Alain [1 ]
Boonaert, Eric [1 ]
Coquelet, Christophe [1 ]
Chapoy, Antonin [1 ,2 ]
机构
[1] PSL Res Univ, CTP, MINES ParisTech, 35 Rue St Honore, F-77300 Fontainebleau, France
[2] Heriot Watt Univ, Inst Petr Engn, Hydrates Flow Assurance & Phase Equilibria, Edinburgh EH14 4AS, Midlothian, Scotland
关键词
VAPOR-LIQUID-EQUILIBRIUM; STATIC-ANALYTIC METHOD; SOLUBILITY MEASUREMENTS; TEMPERATURES; APPARATUS; EQUATIONS; SYSTEM; OXYGEN;
D O I
10.1021/acs.jced.7b00782
中图分类号
O414.1 [热力学];
学科分类号
摘要
Air contains impurities, which must be removed before its transformation and utilization. In the present work, new isothermal vapor-liquid equilibrium (VLE) data are reported for three binary systems containing NO with (CO, N-2, or Ar) at different temperatures (between 105 and 146 K) and pressures up to 4 MPa. The compositions of the coexisting phases were experimentally determined using an apparatus based on the "static-analytic" method. The Peng-Robinson equation of state combined with different mixing rules (classical, Wong-Sandler, and Huron-Vidal) were used to represent the phase diagram (P, x, y).
引用
收藏
页码:1021 / 1026
页数:6
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