Structural isomerism leading to variable proton conductivity in indium(III) isophthalic acid based frameworks

被引:122
作者
Panda, Tamas [1 ]
Kundu, Tanay [1 ]
Banerjee, Rahul [1 ]
机构
[1] CSIR Natl Chem Lab, Phys Mat Chem Div, Pune 411008, Maharashtra, India
关键词
METAL-ORGANIC FRAMEWORK; NAFION; CONDUCTORS; MEMBRANES;
D O I
10.1039/c3cc41939h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Proton conductivity has been studied thoroughly in two isomeric In(III)-isophthalate based MOFs. In-IA-2D-1 is capable of showing proton conductivity (3.4 x 10(-3) S cm(-1)) under humidified conditions (98% RH), whereas In-IA-2D-2 can conduct protons (2.6 x 10(-5) S cm(-1)) under humidified as well as anhydrous conditions.
引用
收藏
页码:6197 / 6199
页数:3
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