A new approach to the Nd residence time in the ocean: the role of atmospheric inputs

Concentrations of rare earth elements (REE) and Nd isotopic ratios were analyzed for seawater, filtered suspension and sediment trap samples collected in the tropical Atlantic Ocean (EUMELI program, EUtrophic, MEsotrophic and oLIgotrophic sites, 20 degrees N, 18 degrees-21 degrees W). This is the first REE/Nd dataset on solution and different-sized particles collected at the same site. We present direct evidence of the Nd isotopic exchange between particulate lithogenic fraction and seawater without significant mass transfer. This exchange is probably one of;he main factors that simultaneously constrains the Nd concentration and isotopic ratio budget. We propose a new approach to estimate the residence time of Nd in the ocean (tau(Nd)) based on isotopic exchange: 200 yr < tau(Nd) < 1000 yr. The exchange requires a partial dissolution of lithogenic Nd. We estimate that the fraction of soluble Nd proportion in atmospheric dust is of the order of 20% based on the isotopic ratios. We suggest that the partial dissolution of atmospheric fallout is probably one of the main REE sources of the ocean. (C) 1999 Elsevier Science B.V. All rights reserved.