Facile synthesis of Fe3O4 nanorod decorated reduced graphene oxide (RGO) for supercapacitor application

被引:71
作者
Das, Ashok Kumar [1 ]
Sahoo, Sumanta [1 ]
Arunachalam, Prabhakarn [2 ]
Zhang, Suojiang [3 ]
Shim, Jae-Jin [1 ]
机构
[1] Yeungnam Univ, Sch Chem Engn, Gyongsan 712749, Gyeongbuk, South Korea
[2] King Saud Univ, Dept Chem, Coll Sci, Electrochem Res Grp, Riyadh 11451, Saudi Arabia
[3] Chinese Acad Sci, Inst Proc Engn, Beijing 100190, Peoples R China
基金
新加坡国家研究基金会;
关键词
HIGH-ENERGY DENSITY; ULTRATHIN NANOSHEETS; PERFORMANCE; NANOCOMPOSITES; ELECTRODES; COMPOSITE; FABRICATION; SHEETS; CAPACITOR; ROUTE;
D O I
10.1039/c6ra23665k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of electrode materials capable of delivering high electrochemical performance is a major challenge. Herein, we demonstrate a facile approach for the synthesis of rod-shaped Fe3O4 nanostructures anchored on the reduced graphene oxide (RGO) surface and its application as an active electrode material for supercapacitors. The RGO-Fe3O4 nanocomposite was prepared by the spontaneous deposition of the rod-like FeOOH nanostructure onto the self-reduced GO surface followed by a thermal annealing process. The physical characterizations demonstrate the decoration of the rod-like Fe3O4 nanostructure over the RGO surface. Morphology analysis demonstrates that Fe3O4 nanorods with an average size of 150 nm are distributed over the RGO surface. The surface area analysis demonstrates that the as-synthesized RGO-Fe3O4 nanorod nanocomposite has 186 m(2) g(-1) specific surface area, which is higher compared to the Fe3O4 nanorods. As an active electrode material, the RGO-Fe3O4 nanocomposite shows excellent electrochemical performance compared to Fe3O4 nanorods. On the RGO-Fe3O4 nanocomposite based electrode a specific capacity of 315 C g(-1) was observed at 5 A g(-1) current density. Additionally, the RGO-Fe3O4 nanocomposite based electrode displayed excellent cycling stability with 95% specific capacity retention after 2000 cycles. The electrochemical results demonstrates that the RGO-Fe3O4 nanocomposite could be a promising material for energy conversion and storage.
引用
收藏
页码:107057 / 107064
页数:8
相关论文
共 59 条
[1]  
[Anonymous], 1999, ELECTROCHEMICAL SUPE
[2]   Fiber Supercapacitors Made of Nanowire-Fiber Hybrid Structures for Wearable/Flexible Energy Storage [J].
Bae, Joonho ;
Song, Min Kyu ;
Park, Young Jun ;
Kim, Jong Min ;
Liu, Meilin ;
Wang, Zhong Lin .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (07) :1683-1687
[3]   Graphene-inorganic nanocomposites [J].
Bai, Song ;
Shen, Xiaoping .
RSC ADVANCES, 2012, 2 (01) :64-98
[4]   To Be or Not To Be Pseudocapacitive? [J].
Brousse, Thierry ;
Belanger, Daniel ;
Long, Jeffrey W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (05) :A5185-A5189
[5]   Microwave-assisted synthesis of NiCo2O4-graphene oxide nanocomposites suitable as electrodes for supercapacitors [J].
Carriazo, Daniel ;
Patino, Julian ;
Gutierrez, Maria C. ;
Luisa Ferrer, M. ;
del Monte, Francisco .
RSC ADVANCES, 2013, 3 (33) :13690-13695
[6]   Graphene Oxide-MnO2 Nanocomposites for Supercapacitors [J].
Chen, Sheng ;
Zhu, Junwu ;
Wu, Xiaodong ;
Han, Qiaofeng ;
Wang, Xin .
ACS NANO, 2010, 4 (05) :2822-2830
[7]   Iodide-mediated room temperature reduction of graphene oxide: a rapid chemical route for the synthesis of a bifunctional electrocatalyst [J].
Das, Ashok Kumar ;
Srivastav, Manish ;
Layek, Rama K. ;
Uddin, Md Elias ;
Jung, Daeseung ;
Kim, Nam Hoon ;
Lee, Joong Hee .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (05) :1332-1340
[8]   Electrochemical Performances of Nanoparticle Fe3O4/Activated Carbon Supercapacitor Using KOH Electrolyte Solution [J].
Du, Xuan ;
Wang, Chengyang ;
Chen, Mingming ;
Jiao, Yang ;
Wang, Jin .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (06) :2643-2646
[9]   Periodic stacking of 2D charged sheets: Self-assembled superlattice of Ni-Al layered double hydroxide (LDH) and reduced graphene oxide [J].
Ge, Xiang ;
Gu, Changdong ;
Yin, Zongyou ;
Wang, Xiuli ;
Tu, Jiangping ;
Li, Ju .
NANO ENERGY, 2016, 20 :185-193
[10]   Graphene: Status and Prospects [J].
Geim, A. K. .
SCIENCE, 2009, 324 (5934) :1530-1534