Carbon dots synthesized at room temperature for detection of tetracycline hydrochloride

被引:219
作者
Yan, Yuan [1 ]
Liu, Jia Hui [2 ]
Li, Rong Sheng [2 ]
Li, Yuan Fang [1 ]
Huang, Cheng Zhi [1 ,2 ]
Zhen, Shu Jun [1 ]
机构
[1] Southwest Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Luminescence & Real Time Analyt Chem, Chongqing 400715, Peoples R China
[2] Southwest Univ, Coll Pharmaceut Sci, Chongqing Sci & Technol Commiss, Chongqing Key Lab Biomed Anal, Chongqing 400715, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon dots; Room temperature synthesis; Tetracycline; VISIBLE-LIGHT-DRIVEN; QUANTUM DOTS; HIGHLY FLUORESCENT; RESIDUES; NANODOTS; CORE;
D O I
10.1016/j.aca.2019.02.047
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The traditional synthesis methods of carbon dots (CDs) have some disadvantages of complicated operation and a large amount of energy consumption. To address these limitations, we synthesized yellow-green luminescent CDs at room temperature according to the principle of amine-aldehyde condensation in this work. This reaction is simple, economical, energy saving and is extremely consistent with the concept of green synthesis and sustainable development. In addition, studies have found that tetracycline hydrochloride (TC) can quench the fluorescence of the as-prepared CDs through Inner filter effect (IFE). The changes of the fluorescence intensity also have a good linear relationship with the concentration of TC in the range of 10.0-400.0 mu M, and the detection limit is 6.0 mu M. This method has been successfully used to determine the tetracycline content of tetracycline tablets. Finally, the interaction mechanism between TC and CDs was analyzed and discussed. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:144 / 151
页数:8
相关论文
共 38 条
[1]   Hydrothermal synthesis of highly fluorescent and non-toxic carbon dots using Stevia rebaudiana Bertoni [J].
Ansari, Fatemeh ;
Kahrizi, Danial .
CELLULAR AND MOLECULAR BIOLOGY, 2018, 64 (12) :32-36
[2]   A large-scale synthesis of photoluminescent carbon quantum dots: a self-exothermic reaction driving the formation of the nanocrystalline core at room temperature [J].
Chen, Bin Bin ;
Liu, Ze Xi ;
Deng, Wen Chan ;
Zhan, Lei ;
Liu, Meng Li ;
Huang, Cheng Zhi .
GREEN CHEMISTRY, 2016, 18 (19) :5127-5132
[3]   Highly selective detection of 2,4,6-trinitrophenol by using newly developed terbium-doped blue carbon dots [J].
Chen, Bin Bin ;
Liu, Ze Xi ;
Zou, Hong Yan ;
Huang, Cheng Zhi .
ANALYST, 2016, 141 (09) :2676-2681
[4]  
Chen CL, 1995, J AOAC INT, V78, P1369
[5]   Full-Color Light-Emitting Carbon Dots with a Surface-State-Controlled Luminescence Mechanism [J].
Ding, Hui ;
Yu, Shang-Bo ;
Wei, Ji-Shi ;
Xiong, Huan-Ming .
ACS NANO, 2016, 10 (01) :484-491
[6]   A surfactant-assisted redox hydrothermal route to prepare highly photoluminescent carbon quantum dots with aggregation-induced emission enhancement properties [J].
Gao, Ming Xuan ;
Liu, Chun Fang ;
Wu, Zhu Lian ;
Zeng, Qiao Ling ;
Yang, Xiao Xi ;
Wu, Wen Bi ;
Li, Yuan Fang ;
Huang, Cheng Zhi .
CHEMICAL COMMUNICATIONS, 2013, 49 (73) :8015-8017
[7]   PYRIDOXINE AND PYRIDOXAL ANALOGS .5. SYNTHESES AND INFRARED SPECTRA OF SCHIFF BASES [J].
HEINERT, D ;
MARTELL, AE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (17) :3257-&
[8]   An active structure preservation method for developing functional graphitic carbon dots as an effective antibacterial agent and a sensitive pH and Al(III) nanosensor [J].
Hou, Peng ;
Yang, Tong ;
Liu, Hui ;
Li, Yuan Fang ;
Huang, Cheng Zhi .
NANOSCALE, 2017, 9 (44) :17334-17341
[9]   Dual-Color-Emitting Carbon Nanodots for Multicolor Bioimaging and Optogenetic Control of Ion Channels [J].
Kim, Hyemin ;
Park, Yoonsang ;
Beack, Songeun ;
Han, Seulgi ;
Jung, Dooyup ;
Cha, Hyung Joon ;
Kwon, Woosung ;
Hahn, Sei Kwang .
ADVANCED SCIENCE, 2017, 4 (11)
[10]   Carbon dots based FRET for the detection of DNA damage [J].
Kudr, Jiri ;
Richtera, Lukas ;
Xhaxhiu, Kledi ;
Hynek, David ;
Heger, Zbynek ;
Zitka, Ondrej ;
Adam, Vojtech .
BIOSENSORS & BIOELECTRONICS, 2017, 92 :133-139