Silver(I) Complexes of Bisphosphines PhN{P(OC6H4C3H5-o)2}2 (1) and 2,6-{Ph2PC(O)}2C5H3N (2)

被引：1

作者：

Kashid, Vitthalrao S. ^{[1
]}

Naik, Susmita ^{[1
]}

Balakrishna, Maravanji S. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Phosphorus Lab, Bombay 400076, Maharashtra, India

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES INDIA SECTION A-PHYSICAL SCIENCES | 2016年 / 86卷 / 04期

关键词：

Bisphosphine; Silver(I); Bidentate ligand; Coordination chemistry; GROUP-11; METAL-COMPLEXES; CATALYTIC INVESTIGATIONS; COORDINATION POLYMERS; DIPHOSPHINE LIGANDS; COPPER(I) COMPLEXES; DFT CALCULATIONS; PNP LIGAND; TETRANUCLEAR; PHENYLAMINOBIS(PHOSPHONITE); PHN(P(OC6H4OME-O)(2))(2);

D O I：

10.1007/s40010-016-0309-6

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Silver complexes of two bisphosphine ligands, PhN{P(OC6H4C3H5-o)(2)}(2) (1) and 2,6-{Ph2PC(O)}(2)C5H3N (2) have been described. Reactions of bisphosphines 1 and 2 with silver salts produce either mononuclear or dinuclear complexes (3-6) depending on the stoichiometry of the reagents and the reaction conditions. All new complexes have been characterized by spectroscopic and analytical data. The structure of spirocyclic complex, [Ag{2,6-{Ph2PC(O)}(2)C5H3N}(2)][CF3SO3] (6) has been confirmed by single crystal X-ray analysis.

引用

页码：601 / 604

页数：4

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