Nickel(II) and zinc(II) complexes of a pyridine ligand bearing a tetrathiafulvalene substituent

被引：3

作者：

Xiao, Xun-wen ^{[1
]}

He, Yan-jun ^{[1
,2
]}

Sun, Li-wen ^{[1
]}

Wang, Guan-nan ^{[1
,2
]}

Shen, Liang-jun ^{[1
]}

Fang, Jiang-hua ^{[1
]}

Gao, Hao-qi ^{[1
]}

Yang, Jian-ping ^{[1
]}

机构：

[1] Ningbo Univ Technol, Dept Chem Engn, Ningbo 315016, Zhejiang, Peoples R China

[2] Taiyuan Univ Technol, Dept Chem & Chem Engn, Taiyuan 030024, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 08期

基金：

中国国家自然科学基金;

关键词：

INTRAMOLECULAR CHARGE-TRANSFER; CRYSTAL-STRUCTURE; TTF DERIVATIVES; ELECTROCHEMICAL PROPERTIES; COORDINATION; COMPOUND; METALS;

D O I：

10.1007/s11243-012-9650-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, crystal structures, and electrochemical properties of the coordination complexes, NiBr2(ept)(2) and ZnBr2(ept)(2) (ept = 4,5-ethylenedioxy-3'-(3'-pyridyl)-tetrathiafulvalene) are reported. Both complexes are mononuclear, with monodentate coordination of the ept ligand through the pyridine nitrogen. Cyclic voltammetry measurements for both complexes show a sizable interaction involving the electroactive ept ligand, with stabilization of the oxidized forms of the complexes.

引用

页码：771 / 775

页数：5

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