Nickel(II) and zinc(II) complexes of a pyridine ligand bearing a tetrathiafulvalene substituent

被引：3
|
作者：
Xiao, Xun-wen [1 ]
He, Yan-jun [1 ,2 ]
Sun, Li-wen [1 ]
Wang, Guan-nan [1 ,2 ]
Shen, Liang-jun [1 ]
Fang, Jiang-hua [1 ]
Gao, Hao-qi [1 ]
Yang, Jian-ping [1 ]
机构：
[1] Ningbo Univ Technol, Dept Chem Engn, Ningbo 315016, Zhejiang, Peoples R China
[2] Taiyuan Univ Technol, Dept Chem & Chem Engn, Taiyuan 030024, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2012年 / 37卷 / 08期
基金：
中国国家自然科学基金;
关键词：
INTRAMOLECULAR CHARGE-TRANSFER; CRYSTAL-STRUCTURE; TTF DERIVATIVES; ELECTROCHEMICAL PROPERTIES; COORDINATION; COMPOUND; METALS;
D O I：
10.1007/s11243-012-9650-z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, crystal structures, and electrochemical properties of the coordination complexes, NiBr2(ept)(2) and ZnBr2(ept)(2) (ept = 4,5-ethylenedioxy-3'-(3'-pyridyl)-tetrathiafulvalene) are reported. Both complexes are mononuclear, with monodentate coordination of the ept ligand through the pyridine nitrogen. Cyclic voltammetry measurements for both complexes show a sizable interaction involving the electroactive ept ligand, with stabilization of the oxidized forms of the complexes.
引用
收藏
页码：771 / 775
页数：5
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