Concepts for improving hydrogen storage in nanoporous materials

被引:201
作者
Broom, D. P. [1 ]
Webb, C. J. [2 ]
Fanourgakis, G. S. [3 ]
Froudakis, G. E. [3 ]
Trikalitis, P. N. [3 ]
Hirscher, M. [4 ]
机构
[1] Hiden Isochema Ltd, 422 Europa Blvd, Warrington WA5 7TS, Cheshire, England
[2] Griffith Univ, Queensland Micro & Nanotechnol Ctr, Brisbane, Qld, Australia
[3] Univ Crete, Dept Chem, POB 2208, Iraklion 71003, Crete, Greece
[4] Max Planck Inst Intelligente Syst, Heisenbergstr 3, D-70569 Stuttgart, Germany
关键词
Hydrogen storage materials; Hydrogen adsorption; Nanoporous materials; Metal-organic frameworks; Machine learning; METAL-ORGANIC FRAMEWORKS; ULTRAHIGH SURFACE-AREA; TARGETED SYNTHESIS; POROUS MATERIALS; METHANE STORAGE; FUEL-CELL; ADSORPTION; DENSITY; MOF-5; INTERPENETRATION;
D O I
10.1016/j.ijhydene.2019.01.224
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen storage in nanoporous materials has been attracting a great deal of attention in recent years, as high gravimetric H-2 capacities, exceeding 10 wt% in some cases, can be achieved at 77 K using materials with particularly high surface areas. However, volumetric capacities at low temperatures, and both gravimetric and volumetric capacities at ambient temperature, need to be improved before such adsorbents become practically viable. This article therefore discusses approaches to increasing the gravimetric and volumetric hydrogen storage capacities of nanoporous materials, and maximizing the usable capacity of a material between the upper storage and delivery pressures. In addition, recent advances in machine learning and data science provide an opportunity to apply this technology to the search for new materials for hydrogen storage. The large number of possible component combinations and substitutions in various porous materials, including Metal-Organic Frameworks (MOFs), is ideally suited to a machine learning approach; so this is also discussed, together with some new material types that could prove useful in the future for hydrogen storage applications. (C) 2019 The Authors. Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.
引用
收藏
页码:7768 / 7779
页数:12
相关论文
共 118 条
[1]   Automotive hydrogen storage system using cryo-adsorption on activated carbon [J].
Ahluwalia, R. K. ;
Peng, J. K. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (13) :5476-5487
[2]   Balancing gravimetric and volumetric hydrogen density in MOFs [J].
Ahmed, Alauddin ;
Liu, Yiyang ;
Purewal, Justin ;
Tran, Ly D. ;
Wong-Foy, Antek G. ;
Veenstra, Mike ;
Matzger, Adam J. ;
Siegel, Donald J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (11) :2459-2471
[3]   An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage [J].
Allendorf, Mark D. ;
Hulvey, Zeric ;
Gennett, Thomas ;
Ahmed, Alauddin ;
Autrey, Tom ;
Camp, Jeffrey ;
Cho, Eun Seon ;
Furukawa, Hiroyasu ;
Haranczyk, Maciej ;
Head-Gordon, Martin ;
Jeong, Sohee ;
Karkamkar, Abhi ;
Liu, Di-Jia ;
Long, Jeffrey R. ;
Meihaus, Katie R. ;
Nayyar, Iffat H. ;
Nazarov, Roman ;
Siegel, Donald J. ;
Stavila, Vitalie ;
Urban, Jeffrey J. ;
Veccham, Srimukh Prasad ;
Wood, Brandon C. .
ENERGY & ENVIRONMENTAL SCIENCE, 2018, 11 (10) :2784-2812
[4]   Volumetric hydrogen adsorption capacity of densified MIL-101 monoliths [J].
Ardelean, Ovidiu ;
Blanita, Gabriela ;
Borodi, Gheorghe ;
Lazar, Mihaela D. ;
Misan, Ioan ;
Coldea, Ioan ;
Lupu, Dan .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (17) :7046-7055
[5]   Optimal isosteric heat of adsorption for hydrogen storage and delivery using metal-organic frameworks [J].
Bae, Youn-Sang ;
Snurr, Randall Q. .
MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 132 (1-2) :300-303
[6]   Volumetric Hydrogen Storage Capacity in Metal-Organic Frameworks [J].
Balderas-Xicohtencatl, R. ;
Schlichtenmayer, Maurice ;
Hirscher, Michael .
ENERGY TECHNOLOGY, 2018, 6 (03) :578-582
[7]   High Volumetric Hydrogen Storage Capacity using Interpenetrated Metal-Organic Frameworks [J].
Balderas-Xicohtencatl, Rafael ;
Schmieder, Phillip ;
Denysenko, Dmytro ;
Volkmer, Dirk ;
Hirscher, Michael .
ENERGY TECHNOLOGY, 2018, 6 (03) :510-512
[8]   Assessment of hydrogen storage by physisorption in porous materials [J].
Bastos-Neto, Moises ;
Patzschke, Christin ;
Lange, Marcus ;
Moellmer, Jens ;
Moeller, Andreas ;
Fichtner, Sven ;
Schrage, Christian ;
Laessig, Daniel ;
Lincke, Joerg ;
Staudt, Reiner ;
Krautscheid, Harald ;
Glaeser, Roger .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (08) :8294-8303
[9]   Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area [J].
Ben, Teng ;
Ren, Hao ;
Ma, Shengqian ;
Cao, Dapeng ;
Lan, Jianhui ;
Jing, Xiaofei ;
Wang, Wenchuan ;
Xu, Jun ;
Deng, Feng ;
Simmons, Jason M. ;
Qiu, Shilun ;
Zhu, Guangshan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) :9457-9460
[10]   Optimum conditions for adsorptive storage [J].
Bhatia, SK ;
Myers, AL .
LANGMUIR, 2006, 22 (04) :1688-1700