Formation of different framework structured dimeric dianions formed from the reduction of 2,4,6-tricyano-1,3,5-triazine and 1,3,5-tricyanobenzene

被引：13

作者：

Del Sesto, RE ^{[1
]}

Arif, AM ^{[1
]}

Miller, JS ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108297n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of 2,4,6-tricyano-1,3,5-triazine (1) and 1,3,5-tricyanobenzene (2) leads to dianionic dimers with long, similar to 1.57 Angstrom, central C-C bonds. In contrast to 1, which dimerizes at the nitrile substituted carbon, 2 has a different motif as it dimerizes at the hydrogen substituted carbon.

引用

页码：2730 / 2731

页数：2

共 21 条

[1]

[Anonymous], 1987, INTRO SYNTHETIC ELEC

[2]

[Anonymous], MECH THEORY ORGANIC

[3]

Bard A.J., 1989, ELECTROANALYTICAL CH, P181

[4] ISOLATION AND STRUCTURAL DETERMINATION OF ((1,1,2,2-TETRACYANO-1,2-ETHANEDIYL)BIS[IMINO(CYANOMETHYLENE)])BIS(CYANAMIDE) ION(2-), [C12N12](2-), A NEW CYANOCARBON [J].