Formation of different framework structured dimeric dianions formed from the reduction of 2,4,6-tricyano-1,3,5-triazine and 1,3,5-tricyanobenzene

被引：13
|
作者：
Del Sesto, RE [1 ]
Arif, AM [1 ]
Miller, JS [1 ]
机构：
[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 24期
关键词：
D O I：
10.1039/b108297n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reduction of 2,4,6-tricyano-1,3,5-triazine (1) and 1,3,5-tricyanobenzene (2) leads to dianionic dimers with long, similar to 1.57 Angstrom, central C-C bonds. In contrast to 1, which dimerizes at the nitrile substituted carbon, 2 has a different motif as it dimerizes at the hydrogen substituted carbon.
引用
收藏
页码：2730 / 2731
页数：2
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