Methane hydroxylation: a biomimetic approach

被引：27

作者：

Shilov, A. E. ^{[1
]}

Shteinman, A. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2012年 / 81卷 / 04期

关键词：

C-H BOND; FE-2(MU-O)(2) DIAMOND CORE; DENSITY-FUNCTIONAL THEORY; COENZYME-M REDUCTASE; METHYLOCOCCUS-CAPSULATUS BATH; NONHEME IRON CATALYSTS; STEREOSPECIFIC ALKANE HYDROXYLATION; LOW-TEMPERATURE OXIDATION; DINUCLEAR COPPER CENTER; SOLUBLE METHANE;

D O I：

10.1070/RC2012v081n04ABEH004271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The review addresses direct methane oxidation - an important fundamental problem,which has attracted much attention of researchers in recent years. Analysis of the available results on biomimetic and bio-inspired methane oxygenation has demonstrated that assimilating of the experience of Nature on oxidation of methane and other alkanes significantly enriches the arsenal of chemistry and can radically change the character of the entire chemical production,as well as enables the solution of many material,energetic and environmental problems. The bibliography includes 310 references.

引用

页码：291 / 316

页数：26

共 314 条

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