Determination of traces of uranium and thorium in titanium and copper used for the construction of the Russian Emission Detector 100 by inductively coupled plasma mass spectrometry

The Russian Emission Detector 100 (RED-100) under construction at the National Research Nuclear University MEPhI (Moscow Engineering Physics Institute) is designed to detect the presently undiscovered effect of coherent neutrino scattering. One of the factors limiting the sensitivity of the detector is the spontaneous decay of uranium and thorium in the detector materials. Radioactive impurities in detector materials at levels of parts per billion can significantly affect the sensitivity. Five random samples of titanium and one of copper-from materials used in the construction of the detector were selected for assay. The concentrations of Th-232 and U-238 were measured by inductively coupled plasma mass spectrometry (ICP-MS) in solid titanium using both solutions in acids and direct sampling by laser ablation (LA-ICP-MS). The LA-ICP-MS method allowed us to determine U-238 and Th-232 at subnanogram per gram levels. This method is much faster than ICP-MS with liquid injection. The titanium samples studied have impurities in the range between 1 ng g(-1) and 21 ng g(-1) for U-238 and 3 ng g(-1) and 31 ng g(-1) for Th-232. In copper we set upper limits of 0.4 ng g(-1) for U-238 and 1 ng g(-1) for Th-232. The total activity of the cryostat constructed from the materials studied was estimated to be 43 Bq.